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作为盐酸溶液中天然生成的铜腐蚀抑制剂的费氏芦荟提取物的热力学、化学和电化学研究

Thermodynamic, chemical, and electrochemical studies of Aloe ferox Mill extract as a naturally developing copper corrosion inhibitor in HCl solution.

作者信息

Alanazi Kaseb D, Alshammari Basmah H, Alanazi Tahani Y A, Alshammari Odeh A O, Ashmawy Ashraf M, Aljohani Meshari M, Haq Isma, Hameed Reda Abdel, Deyab M A

机构信息

Department of Chemistry, College of Science, University of Ha'il, 81442, Hail, Saudi Arabia.

Chemistry Department, Faculty of Science (boys), Al-Azhar University, Cairo, 11884, Egypt.

出版信息

Sci Rep. 2024 May 24;14(1):11944. doi: 10.1038/s41598-024-62169-x.

Abstract

Copper can be susceptible to corrosion in acidic cleaning solutions for desalination system, especially if the solution is highly concentrated or if the cleaning process involves extended exposure to the acid. In the current work, Aloe ferox Mill (AFM extract) can be used as a natural origin corrosion inhibitor for copper in 1.0 M HCl solution. The corrosion mitigation qualities of AFM extract were assessed by means of electrochemical, gravimetric, and surface examinations. AFM extract is a mixed-type inhibitor, based on polarization research findings. The inhibitory effectiveness of AFM extract rises with concentration, reaching its maximum level (93.3%) at 250 mg L. The inclusion of AFM extract raises the activation energy for the corrosion reaction from 7.15 kJ mol (blank solution) to 28.6 kJ mol (at 250 mg L AFM extract).

摘要

在用于海水淡化系统的酸性清洗溶液中,铜可能易受腐蚀,特别是当溶液高度浓缩时,或者清洗过程涉及长时间暴露于酸中时。在当前工作中,费氏芦荟(AFM提取物)可用作1.0 M HCl溶液中铜的天然腐蚀抑制剂。通过电化学、重量法和表面检查评估了AFM提取物的缓蚀性能。根据极化研究结果,AFM提取物是一种混合型抑制剂。AFM提取物的抑制效果随浓度增加而提高,在250 mg/L时达到最高水平(93.3%)。加入AFM提取物使腐蚀反应的活化能从7.15 kJ/mol(空白溶液)提高到28.6 kJ/mol(在250 mg/L AFM提取物时)。

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本文引用的文献

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