Novel AgPO/boron-carbon-nitrogen photocatalyst for highly efficient degradation of organic pollutants under visible-light irradiation.

AgPO is an indirect bandgap semiconductor with excellent photocatalytic activity. However, it has not been widely used so far for the treatment of polluted wastewaters. This scarce use in wastewater treatment can be mainly attributed to its large crystallite size, which would be due to rapid agglomeration during the synthesis process, as well as to the photo-corrosion problem affecting this material. Hence, it would be crucial to develop a photocatalytic system involving AgPO nanoparticles with enhanced properties, such as higher specific surface area and excellent photocatalytic stability. To meet this demand, a novel AgPO/boron carbon nitrogen (AgPO/BCN) composite photocatalyst was successfully prepared in the present study via electrostatically driven self-assembly and ion exchange processes. After characterization and assessment, it was shown that the as-prepared AgPO/BCN nanocomposite photocatalyst not only contains smaller AgPO nanoparticles, but also exhibits an enhanced visible-light photocatalytic activity for Rhodamine B (RhB) Methyl Orange (MO) and Tetracycline (TC) and improved stability, without decrease after 5 cycles, compared with pure AgPO nanoparticles. Positive synergy between AgPO nanoparticles and BCN nanosheets, including the increase in the number of active adsorption sites, and the restriction of the formation of Ag due to the recombination of photogenerated electron-hole pairs in AgPO nanoparticles, are mainly responsible for the enhanced properties of the prepared catalyst. This study shows that AgPO/BCN composite photocatalyst would be promising for wastewater treatment, which would be of clearly environmental and public health relevance.