A novel ratiometric and colorimetric probe for rapid and ultrasensitive detection of nitrite in water based on an Acenaphtho[1,2-d] imidazole derivative.

The concentration of nitrite (NO) ions above allowable limits in water resources and food stuffs is considered hazardous and has been proven to be of great threat to the environment and public health. In this work, an acenaphtho [1,2-d] imidazole derivative (1) as a ratiometric colorimetric probe is developed. UV-Vis experiments demonstrate that the probe 1 shows excellent selectivity toward NO in the presence of other potential interfering species, a rapid response (20 s) and a low detection limit (100 nM) by a distinct visual color change with a bathochromic shift of 120 nm from colorless to intense yellow. Besides, this probe is further used for the quantification of nitrite ions in environmental water resources such as tap water, underground water, and surface water samples. The high recoveries (96-99% with relative standard deviations (RSD) of <2.0%) make the probe 1 a promising candidate for practical applications in daily life in the detection of nitrite ions.