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三（2-二环己基膦基-2′,6′-二甲氧基-1,1′-联苯-κ）-μ-氧代亚乙烯基-三（金（I））双（三氟甲烷磺酰）亚胺的晶体结构

Crystal structure of tris-(2-di-cyclo-hexyl-phosphino-2',6'-dimeth-oxy-1,1'-biphenyl-κ)-μ-oxoethenyl-idene--trigold(I) bis-(tri-fluoro-methane-sulfon-yl)imide.

作者信息

Hartgerink Colin T, Staples Richard J, Anderson Carolyn E

机构信息

Department of Chemistry and Biochemistry, Calvin University, 1726 Knollcrest Circle SE, Grand Rapids, MI 49546, USA.

Center for Crystallographic Research, Department of Chemistry, Michigan State University, 578 S. Shaw Lane, East Lansing, MI 48824, USA.

出版信息

Acta Crystallogr E Crystallogr Commun. 2021 Apr 16;77(Pt 5):537-541. doi: 10.1107/S2056989021003844. eCollection 2021 May 1.

DOI:10.1107/S2056989021003844
PMID:34026260
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8100268/
Abstract

The title ketenyl-idene, Au(CO)(CHOP), was obtained upon exposure of [2-(di-cyclo-hexyl-phosphino)-2',6'-dimeth-oxy-1,1'-biphen-yl]gold(I) bis-(tri-fluoro-methane-sulfon-yl)imide to acetic anhydride at elevated temperature. The ketenyl-idene bridge caps the tri-gold cluster. The title compound has provided crystals that upon analysis represent the first tri-gold ketenyl-idene with atomic distances indicative of bonding inter-action between the gold atoms.

摘要

烯酮基亚甲基Au(CO)(CHOP)这个名称是在高温下将[2-(二环己基膦基)-2',6'-二甲氧基-1,1'-联苯基]金(I)双(三氟甲磺酰)亚胺暴露于乙酸酐时得到的。烯酮基亚甲基桥连接着三核金簇。该标题化合物所提供的晶体经分析代表首个具有表明金原子间存在键合相互作用的原子间距的三核金烯酮基亚甲基化合物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/594a/8100268/c0f3d47be2af/e-77-00537-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/594a/8100268/984a77a12436/e-77-00537-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/594a/8100268/fbd8a14aa97b/e-77-00537-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/594a/8100268/c0f3d47be2af/e-77-00537-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/594a/8100268/984a77a12436/e-77-00537-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/594a/8100268/fbd8a14aa97b/e-77-00537-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/594a/8100268/c0f3d47be2af/e-77-00537-fig3.jpg

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本文引用的文献

1
Au(I)-Catalyzed Synthesis of Trisubstituted Indolizines from 2-Propargyloxypyridines and Methyl Ketones.金（I）催化的 2-炔丙氧基吡啶和甲基酮合成三取代吲哚嗪。
Org Lett. 2019 Jul 19;21(14):5591-5595. doi: 10.1021/acs.orglett.9b01929. Epub 2019 Jul 1.
2
The Cambridge Structural Database.剑桥结构数据库。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):171-9. doi: 10.1107/S2052520616003954. Epub 2016 Apr 1.
3
Localized partial oxidation of acetic acid at the dual perimeter sites of the Au/TiO2 catalyst-formation of gold ketenylidene.
在 Au/TiO2 催化剂的双边界位局部氧化醋酸-形成金烯酮。
J Am Chem Soc. 2012 Aug 22;134(33):13569-72. doi: 10.1021/ja305911e. Epub 2012 Aug 13.
4
Aurophilic interactions as a subject of current research: an up-date.金键相互作用作为当前研究课题：最新进展。
Chem Soc Rev. 2012 Jan 7;41(1):370-412. doi: 10.1039/c1cs15182g. Epub 2011 Aug 24.