Li Wei-Ze, Wang Zhong-Xia
CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China..
Org Biomol Chem. 2021 Jun 16;19(23):5082-5086. doi: 10.1039/d1ob00840d.
Ni(PEt3)Cl2-catalyzed silylation of alkyl aryl sulfoxides with silylzinc reagents was carried out. This protocol allows alkyl aryl sulfoxides to convert to arylsilicon compounds under mild reaction conditions, tolerates a range of functional groups and is suitable for a wide scope of substrates.
进行了二氯（三乙膦）镍催化的烷基芳基亚砜与硅锌试剂的硅烷化反应。该方法能使烷基芳基亚砜在温和的反应条件下转化为芳基硅化合物，可耐受多种官能团，适用于多种底物。
