1,1-二硼烯的硼-赫克反应合成。
Synthesis of 1,1-Diboryl Alkenes Using the Boryl-Heck Reaction.
机构信息
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
出版信息
Org Lett. 2021 Jun 18;23(12):4838-4842. doi: 10.1021/acs.orglett.1c01567. Epub 2021 May 27.
Abstract
The synthesis of 1,1-diboryl alkenes from terminal alkenes is reported. 1,1-Regioselective addition is observed for both conjugated and unconjugated alkenes, allowing for a single method to prepare a wide range of 1,1-diboryl alkenes.
摘要
报道了从末端烯烃合成 1,1-二硼烯的方法。对于共轭和非共轭烯烃，观察到 1,1-区域选择性加成，允许使用单一方法制备广泛的 1,1-二硼烯。
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