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溶剂调控的寡肽两亲物的有序自组装以构建各向异性介观基质。

Solvent-tailored ordered self-assembly of oligopeptide amphiphiles to create an anisotropic meso-matrix.

机构信息

Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central University for Nationalities, Wuhan 430074, China.

School of Pharmaceutical Sciences, South-Central University for Nationalities, Wuhan, 430074, P. R. China.

出版信息

Chem Commun (Camb). 2021 Jun 22;57(50):6181-6184. doi: 10.1039/d1cc02034j.

DOI:10.1039/d1cc02034j
PMID:34047742
Abstract

Herein, we have developed a solvent-tailored ordered self-assembly strategy to create anisotropic nanomaterials. A trace amount of water has been found to be a predominant factor to direct peptide self-assembly into an anisotropic meso-matrix in DMSO. The obtained meso-matrix was applied to measure the anisotropic RDC parameter of organic molecules for structural elucidation.

摘要

在这里,我们开发了一种溶剂定制的有序自组装策略来创建各向异性纳米材料。已经发现痕量的水是指导肽在 DMSO 中自组装成各向异性介观基质的主要因素。所得到的介观基质被用于测量有机分子的各向异性 RDC 参数以进行结构阐明。

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