• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

膦酸化碳纳米管的合成：碳纳米管功能化的新见解。

Synthesis of Phosphonated Carbon Nanotubes: New Insight into Carbon Nanotubes Functionalization.

作者信息

Nadolska Małgorzata, Prześniak-Welenc Marta, Łapiński Marcin, Sadowska Kamila

机构信息

Institute of Nanotechnology and Materials Engineering, Gdansk University of Technology, 80-233 Gdansk, Poland.

Institute of Biocybernetics, Biomedical Engineering of the Polish Academy of Sciences, 02-109 Warsaw, Poland.

出版信息

Materials (Basel). 2021 May 21;14(11):2726. doi: 10.3390/ma14112726.

DOI:10.3390/ma14112726
PMID:34064192
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8196758/
Abstract

Carbon nanotubes were successfully functionalized for the first time in a free radical phosphonylation reaction. Three synthetic protocols were proposed. Carbon nanotubes and diethylphosphite reacted in the presence of known radical initiator, such as azobisisobutyronitrile, single electron oxidant-Mn(OAc), or under UV radiation. The functionalized material was fully characterized by means of spectroscopic methods, together with microscopic, surface area and thermogravimetric analyses. UV-illumination was found to be the most effective approach for introducing phosphonates onto carbon nanotubes. X-ray photoelectron spectroscopy analysis showed 6% phosphorus in this sample. Moreover, the method was performed at room temperature for only one hour, using diethylphosphite as a reactant and as a solvent. The functionalized carbon nanotubes showed an improved thermal stability, with a decomposition onset temperature increase of more than 130 °C. This makes it very promising material for flame retarding applications.

摘要

碳纳米管首次在自由基膦酰化反应中成功实现功能化。提出了三种合成方案。碳纳米管与亚磷酸二乙酯在已知自由基引发剂（如偶氮二异丁腈）、单电子氧化剂 - 醋酸锰存在下反应，或在紫外辐射下反应。通过光谱方法以及显微镜、表面积和热重分析对功能化材料进行了全面表征。发现紫外光照是将膦酸酯引入碳纳米管的最有效方法。X射线光电子能谱分析表明该样品中磷含量为6%。此外，该方法在室温下仅需一小时，使用亚磷酸二乙酯作为反应物和溶剂。功能化碳纳米管表现出更高的热稳定性，分解起始温度提高了超过130°C。这使其成为用于阻燃应用的非常有前景的材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/7e635a1fc74e/materials-14-02726-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/b2d66f28dbcd/materials-14-02726-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/88c57580528a/materials-14-02726-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/0b50d5b9b356/materials-14-02726-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/51fec9e7ad56/materials-14-02726-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/4c5028c8ec19/materials-14-02726-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/3786221e56d5/materials-14-02726-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/69c825f3911f/materials-14-02726-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/7e635a1fc74e/materials-14-02726-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/b2d66f28dbcd/materials-14-02726-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/88c57580528a/materials-14-02726-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/0b50d5b9b356/materials-14-02726-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/51fec9e7ad56/materials-14-02726-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/4c5028c8ec19/materials-14-02726-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/3786221e56d5/materials-14-02726-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/69c825f3911f/materials-14-02726-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e10/8196758/7e635a1fc74e/materials-14-02726-g008.jpg

相似文献

1
Synthesis of Phosphonated Carbon Nanotubes: New Insight into Carbon Nanotubes Functionalization.膦酸化碳纳米管的合成：碳纳米管功能化的新见解。
Materials (Basel). 2021 May 21;14(11):2726. doi: 10.3390/ma14112726.
2
Modification of multi-walled carbon nanotubes by Diels-Alder and Sandmeyer reactions.通过狄尔斯-阿尔德反应和桑德迈尔反应对多壁碳纳米管进行改性。
J Nanosci Nanotechnol. 2007 Aug;7(8):2795-807. doi: 10.1166/jnn.2007.625.
3
Synthesis and characterization of alkyl ester functionalized multiwall carbon nanotubes.烷基酯功能化多壁碳纳米管的合成与表征
J Nanosci Nanotechnol. 2014 Aug;14(8):6347-54. doi: 10.1166/jnn.2014.8854.
4
Functionalization of carbon nanotubes via dissolving metal reductions.通过金属溶解还原法对碳纳米管进行功能化修饰
J Nanosci Nanotechnol. 2007 Apr-May;7(4-5):1551-9. doi: 10.1166/jnn.2007.339.
5
Flame Retardancy and Dispersion of Functionalized Carbon Nanotubes in Thiol-Ene Nanocomposites.功能化碳纳米管在硫醇-烯纳米复合材料中的阻燃性及分散性
Polymers (Basel). 2021 Sep 28;13(19):3308. doi: 10.3390/polym13193308.
6
Synthesis and thermal transport studies of nanofluids based on metal decorated photochemically oxidized multiwalled carbon nanotubes.基于金属修饰的光化学氧化多壁碳纳米管的纳米流体的合成与热输运研究
J Nanosci Nanotechnol. 2012 Aug;12(8):6615-20. doi: 10.1166/jnn.2012.4540.
7
Preparation and characterization of sulfonic acid-functionalized single-walled carbon nanotubes.磺酸功能化单壁碳纳米管的制备与表征
Physica E Low Dimens Syst Nanostruct. 2009 Feb;41(4):723-728. doi: 10.1016/j.physe.2008.11.018.
8
Planning Implications Related to Sterilization-Sensitive Science Investigations Associated with Mars Sample Return (MSR).与火星样本返回（MSR）相关的对灭菌敏感的科学研究的规划意义。
Astrobiology. 2022 Jun;22(S1):S112-S164. doi: 10.1089/AST.2021.0113. Epub 2022 May 19.
9
A bio-based, facile approach for the preparation of covalently functionalized carbon nanotubes aqueous suspensions and their potential as heat transfer fluids.一种基于生物的、简便的方法，用于制备共价功能化碳纳米管水悬浮液及其作为传热流体的潜力。
J Colloid Interface Sci. 2017 Oct 15;504:115-123. doi: 10.1016/j.jcis.2017.03.051. Epub 2017 Mar 14.
10
Synthesis and Structural Studies of New Selenium Derivatives Based on Covalent Functionalization of MWCNTs.基于 MWCNTs 共价功能化的新型硒衍生物的合成与结构研究。
Int J Mol Sci. 2023 Feb 7;24(4):3299. doi: 10.3390/ijms24043299.

引用本文的文献

1
Structure-activity relationship of Cu-based catalysts for the highly efficient CO electrochemical reduction reaction.用于高效CO电化学还原反应的铜基催化剂的构效关系
Front Chem. 2023 Feb 9;11:1141453. doi: 10.3389/fchem.2023.1141453. eCollection 2023.

本文引用的文献

1
Synthesis of oxygen functionalized carbon nanotubes and their application for selective catalytic reduction of NO with NH.氧功能化碳纳米管的合成及其在NH₃选择性催化还原NO中的应用
RSC Adv. 2020 Apr 28;10(28):16700-16708. doi: 10.1039/d0ra01665a. eCollection 2020 Apr 23.
2
Influence of Oxygen-Containing Functional Groups on the Environmental Properties, Transformations, and Toxicity of Carbon Nanotubes.含氧官能团对碳纳米管环境行为、转化和毒性的影响。
Chem Rev. 2020 Oct 28;120(20):11651-11697. doi: 10.1021/acs.chemrev.0c00351. Epub 2020 Sep 22.
3
Photochemical Rearrangement of a 19-Membered Azoxybenzocrown: Products and their Properties.
19 员氮氧杂冠醚的光化学重排：产物及其性质。
Chempluschem. 2020 Sep;85(9):2067-2083. doi: 10.1002/cplu.202000474.
4
Challenges and opportunities in functional carbon nanotubes for membrane-based water treatment and desalination.功能化碳纳米管在基于膜的水处理和脱盐中的挑战与机遇。
Sci Total Environ. 2019 Jan 1;646:1126-1139. doi: 10.1016/j.scitotenv.2018.07.348. Epub 2018 Jul 25.
5
Carbon Nanotube Chemical Sensors.碳纳米管化学传感器。
Chem Rev. 2019 Jan 9;119(1):599-663. doi: 10.1021/acs.chemrev.8b00340. Epub 2018 Sep 18.
6
Synthesis, characterization, and interactions of single-walled carbon nanotubes modified with doxorubicin with Langmuir-Blodgett biomimetic membranes.阿霉素修饰的单壁碳纳米管与朗缪尔-布洛杰特仿生膜的合成、表征及相互作用
J Nanopart Res. 2018;20(5):143. doi: 10.1007/s11051-018-4239-x. Epub 2018 May 12.
7
Adsorption of tetracycline antibiotics from aqueous solutions on nanocomposite multi-walled carbon nanotube functionalized MIL-53(Fe) as new adsorbent.纳米复合多壁碳纳米管功能化 MIL-53(Fe)作为新型吸附剂从水溶液中吸附四环素类抗生素。
Sci Total Environ. 2018 Jun 15;627:235-244. doi: 10.1016/j.scitotenv.2018.01.249. Epub 2018 Feb 3.
8
Phosphonic acid: preparation and applications.膦酸：制备与应用
Beilstein J Org Chem. 2017 Oct 20;13:2186-2213. doi: 10.3762/bjoc.13.219. eCollection 2017.
9
Designer carbon nanotubes for contaminant removal in water and wastewater: A critical review.用于水和废水中污染物去除的设计碳纳米管：批判性评价。
Sci Total Environ. 2018 Jan 15;612:561-581. doi: 10.1016/j.scitotenv.2017.08.132. Epub 2017 Sep 1.
10
Overview on the Surface Functionalization Mechanism and Determination of Surface Functional Groups of Plasma Treated Carbon Nanotubes.等离子体处理碳纳米管的表面功能化机制及表面官能团的测定概述。
Crit Rev Anal Chem. 2018 Jan 2;48(1):1-14. doi: 10.1080/10408347.2017.1356699. Epub 2017 Sep 14.