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等离子体处理碳纳米管的表面功能化机制及表面官能团的测定概述。

Overview on the Surface Functionalization Mechanism and Determination of Surface Functional Groups of Plasma Treated Carbon Nanotubes.

机构信息

a School of Health , Siirt University , Siirt , Turkey.

出版信息

Crit Rev Anal Chem. 2018 Jan 2;48(1):1-14. doi: 10.1080/10408347.2017.1356699. Epub 2017 Sep 14.

DOI:10.1080/10408347.2017.1356699
PMID:28722465
Abstract

The use of carbon materials for many applications is due to the unique diversity of structures and properties ranging from chemical bonds between the carbon atoms of the materials to nanostructures, crystallite alignment, and microstructures. Carbon nanotubes and other nanoscale carbonaceous materials draw much attention due to their physical and chemical properties, such as high strength, high resistance to corrosion, electrical and thermal conductivity, stability and a qualified adsorbent. Carbon-based nanomaterials, which have a relatively large specific area and layered structure, can be used as an adsorbent for efficient removal of organic and inorganic contaminants. However, one of the biggest obstacles to the development of carbon-based nanomaterials adsorbents is insolubility and the lack of functional groups on the surface. There are several approaches to introduce functional groups on carbon nanotubes. One of these approaches, plasma applications, now has an important place in the creation of surface functional groups as a flexible, fast, and environmentally friendly method. This review focuses on recent information concerning the surface functionalization and modification of plasma treated carbon nanotube. This review considers the surface properties, advantages, and disadvantages of plasma-applied carbon nanotubes. It also examines the reaction mechanisms involved in the functional groups on the surface.

摘要

由于材料中碳原子之间的化学键到纳米结构、晶粒取向和微观结构等结构和性质的独特多样性,碳材料在许多应用中得到了广泛的应用。碳纳米管和其他纳米级碳质材料由于其物理和化学性质而受到广泛关注,例如高强度、高耐腐蚀性、电导率和热导率、稳定性和合格的吸附剂。具有较大比表面积和层状结构的基于碳的纳米材料可用作高效去除有机和无机污染物的吸附剂。然而,碳基纳米材料吸附剂发展的最大障碍之一是其不溶性和表面缺乏官能团。有几种方法可以在碳纳米管上引入官能团。其中一种方法是等离子体应用,它作为一种灵活、快速和环保的方法,现在在表面官能团的形成中占有重要地位。本综述重点介绍了等离子体处理碳纳米管表面功能化和改性的最新信息。本综述考虑了等离子体处理碳纳米管的表面性质、优点和缺点,以及表面官能团涉及的反应机制。

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