Huu Phuc Dang, Thanh Tung Ha, Nguyen Van-Cuong, Hanh Nguyen Thi My
Laboratory of Applied Physics, Advanced Institute of Materials Science, Ton Duc Thang University, Ho Chi Minh City 70880, Vietnam.
Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 70880, Vietnam.
Molecules. 2021 May 12;26(10):2865. doi: 10.3390/molecules26102865.
In this study, TiO/CdS/CdCuSe, TiO/CdS/CdMnSe, and TiO/CdS/CdAgSe thin films were synthesized by chemical bath deposition for the fabrication of photoanode in quantum-dot-sensitized solar cells. As a result, the structural properties of the thin films have been studied by X-ray diffraction, which confirmed the zinc Blende structure in the samples. The optical films were researched by their experimental absorption spectra with different doping concentrations. Those results were combined with the Tauc correlation to estimate the absorption density, the band gap energy, valence band and conduction band positions, steepness parameter, and electron-phonon interaction. Furthermore, the electrical features, electrochemical impedance spectrum and photocurrent density curves were carried out. The result was used to explain the enhancing performance efficiency.
在本研究中,通过化学浴沉积法合成了TiO/CdS/CdCuSe、TiO/CdS/CdMnSe和TiO/CdS/CdAgSe薄膜,用于制备量子点敏化太阳能电池的光阳极。结果,通过X射线衍射研究了薄膜的结构特性,证实了样品中的闪锌矿结构。通过不同掺杂浓度的实验吸收光谱对光学薄膜进行了研究。将这些结果与陶克相关性相结合,以估计吸收密度、带隙能量、价带和导带位置、陡度参数以及电子-声子相互作用。此外,还进行了电学特性、电化学阻抗谱和光电流密度曲线的研究。该结果用于解释性能效率的提高。