Institute for Nanotechnology & Advanced Materials, Department of Chemistry, Bar Ilan University, Ramat Gan 52900, Israel.
Chemphyschem. 2010 Aug 2;11(11):2290-304. doi: 10.1002/cphc.201000069.
Quantum-dot-sensitized solar cells (QDSCs) are a promising low-cost alternative to existing photovoltaic technologies such as crystalline silicon and thin inorganic films. The absorption spectrum of quantum dots (QDs) can be tailored by controlling their size, and QDs can be produced by low-cost methods. Nanostructures such as mesoporous films, nanorods, nanowires, nanotubes and nanosheets with high microscopic surface area, redox electrolytes and solid-state hole conductors are borrowed from standard dye-sensitized solar cells (DSCs) to fabricate electron conductor/QD monolayer/hole conductor junctions with high optical absorbance. Herein we focus on recent developments in the field of mono- and polydisperse QDSCs. Stability issues are adressed, coating methods are presented, performance is reviewed and special emphasis is given to the importance of energy-level alignment to increase the light to electric power conversion efficiency.
量子点敏化太阳能电池(QDSCs)是一种很有前途的低成本替代物,可替代现有的光伏技术,如晶体硅和薄膜无机材料。通过控制量子点(QDs)的尺寸,可以调整其吸收光谱,并且可以通过低成本的方法来制备量子点。介孔薄膜、纳米棒、纳米线、纳米管和纳米片等纳米结构,以及具有高微观表面积的氧化还原电解质和固态空穴导体,都是从标准的染料敏化太阳能电池(DSCs)中借鉴而来,用于制备具有高光吸收的电子导体/量子点单层/空穴导体结。本文重点介绍了单分散和多分散量子点敏化太阳能电池领域的最新进展。文中讨论了稳定性问题,介绍了涂层方法,综述了性能,并特别强调能级对准对于提高光到电力转换效率的重要性。