School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 610054, China.
Sensors (Basel). 2021 May 12;21(10):3385. doi: 10.3390/s21103385.
A complex permittivity characterization method for liquid samples has been proposed. The measurement is carried out based on a self-designed microwave sensor with a split ring resonator (SRR), the unload resonant frequency of which is 5.05 GHz. The liquid samples in capillary are placed in the resonant zone of the fabricated senor for high sensitivity measurement. The frequency shift of 58.7 MHz is achieved when the capillary is filled with ethanol, corresponding a sensitivity of 97.46 MHz/μL. The complex permittivity of methanol, ethanol, isopropanol (IPA) and deionized water at the resonant frequency are measured and calibrated by the first order Debye model. Then, the complex permittivity of different concentrations of aqueous solutions of these materials are measured by using the calibrated sensor system. The results show that the proposed sensor has high sensitivity and accuracy in measuring the complex permittivity of liquid samples with volumes as small as 0.13 μL. It provides a useful reference for the complex permittivity characterization of small amount of liquid chemical samples. In addition, the characterization of an important biological sample (inositol) is carried out by using the proposed sensor.
提出了一种用于液体样品的复介电常数特性化方法。该测量基于具有分裂环谐振器 (SRR) 的自行设计的微波传感器进行,其空载谐振频率为 5.05 GHz。毛细管中的液体样品被放置在制造的传感器的谐振区域内,以进行高灵敏度测量。当毛细管中充满乙醇时,可实现 58.7 MHz 的频率偏移,相应的灵敏度为 97.46 MHz/μL。在谐振频率下,通过一阶 Debye 模型测量并校准甲醇、乙醇、异丙醇 (IPA) 和去离子水的复介电常数。然后,使用校准后的传感器系统测量这些材料的不同浓度的水溶液的复介电常数。结果表明,该传感器在测量体积小至 0.13 μL 的液体样品的复介电常数方面具有高灵敏度和准确性。它为少量液体化学样品的复介电常数特性化提供了有用的参考。此外,还使用所提出的传感器对重要的生物样品(肌醇)进行了特性化。