Pezzana Lorenzo, Malmström Eva, Johansson Mats, Sangermano Marco
Department of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy.
Department of Fibre and Polymer Technology, KTH Royal Institute of Technology, School of Engineering Sciences in Chemistry, Biotechnology and Health, Teknikringen 56-58, SE-100 44 Stockholm, Sweden.
Polymers (Basel). 2021 May 10;13(9):1530. doi: 10.3390/polym13091530.
Bio-based monomers represent the future market for polymer chemistry, since the political economics of different states promote green ventures toward more sustainable materials and processes. Industrial pulp and paper processing represent a large market that could advance the use of by-products to avoid waste production and reduce pollution. Lignin represents the most available side product that can be used to produce a bio-based monomer. This review is concentrated on the possibility of using bio-based monomer derivates from pulp and the paper industry for UV-curing processing. UV-curing represents the new frontier for thermoset production, allowing a fast reaction cure, less energy demand, and the elimination of solvent. The growing demand for new monomers increases research in the environmental field to substitute for petroleum-based products. This review provides an overview of the main monomers and relative families of compounds derived from industrial processes that are suitable for UV-curing. Particular focus is given to the developments reached in the last few years concerning lignin, rosin and terpenes and the related possible applications of these in UV-curing chemistry.
生物基单体代表了聚合物化学的未来市场,因为不同国家的政治经济推动了向更可持续材料和工艺的绿色企业发展。工业制浆造纸加工代表了一个庞大的市场,该市场可以推进副产品的利用,以避免产生废物和减少污染。木质素是最容易获得的副产品,可用于生产生物基单体。本综述集中于使用来自制浆造纸工业的生物基单体衍生物进行紫外光固化加工的可能性。紫外光固化代表了热固性材料生产的新前沿,它能实现快速反应固化、降低能源需求并消除溶剂。对新型单体的需求不断增长,促使环境领域加大研究力度以替代石油基产品。本综述概述了源自工业过程且适用于紫外光固化的主要单体及相关化合物家族。特别关注了过去几年在木质素、松香和萜烯方面取得的进展以及它们在紫外光固化化学中的相关可能应用。