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通过纳米压痕法洞察水与离子交换铝硅酸盐玻璃之间的相互作用

Insight into the Interaction between Water and Ion-Exchanged Aluminosilicate Glass by Nanoindentation.

作者信息

Li Xiaoyu, Jiang Liangbao, Liu Jiaxi, Wang Minbo, Li Jiaming, Yan Yue

机构信息

Department of Transparent Materials, Beijing Institute of Aeronautical Materials, Beijing 100095, China.

Beijing Engineering Research Center of Advanced Structural Transparencies for the Modern Traffic System, Beijing 100095, China.

出版信息

Materials (Basel). 2021 May 30;14(11):2959. doi: 10.3390/ma14112959.

Abstract

This work aims to explore the interaction between water and ion-exchanged aluminosilicate glass. The surface mechanical properties of ion-exchanged glasses after different hydration durations are investigated. The compressive stress and depth of stress layer are determined with a surface stress meter on the basis of photo-elasticity theory. The hardness and Young's modulus are tested through nanoindentation. Infrared spectroscopy is used to determine the variation in surface structures of the glass samples. The results show that hydration has obvious effects on the hardness and Young's modulus of the raw and ion-exchanged glasses. The hardness and Young's modulus decrease to different extents after different hydration times, and the Young's modulus shows some recovery with the prolonging of hydration time. The ion-exchanged glasses are more resistant to hydration. The tin side is more resistant to hydration than the air side. The results are expected to serve as reference for better understanding the hydration process of ion-exchanged glass.

摘要

这项工作旨在探索水与离子交换铝硅酸盐玻璃之间的相互作用。研究了不同水化持续时间后离子交换玻璃的表面力学性能。基于光弹性理论,使用表面应力仪测定压缩应力和应力层深度。通过纳米压痕测试硬度和杨氏模量。利用红外光谱确定玻璃样品表面结构的变化。结果表明,水化对原始玻璃和离子交换玻璃的硬度和杨氏模量有明显影响。不同水化时间后,硬度和杨氏模量有不同程度的降低,且杨氏模量随着水化时间的延长有一定程度的恢复。离子交换玻璃更耐水化。锡面比空气面更耐水化。这些结果有望为更好地理解离子交换玻璃的水化过程提供参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1caa/8198016/1aec441f6eb0/materials-14-02959-g001.jpg

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