Fal Jacek, Bulanda Katarzyna, Oleksy Mariusz, Sobczak Jolanta, Shi Jinwen, Liu Maochang, Boncel Sławomir, Żyła Gaweł
Department of Experimental Physics, Faculty of Mathematics and Applied Physics, Rzeszów University of Technology, 35-959 Rzeszów, Poland.
Department of Polymer Composites, Faculty of Chemistry, Rzeszów University of Technology, 35-959 Rzeszów, Poland.
Materials (Basel). 2021 May 26;14(11):2835. doi: 10.3390/ma14112835.
Two types of graphite/diamond (GD) particles with different ash content was applied to prepare new electroconductive polylactide (PLA)-based nanocomposites. Four samples of nanocomposites for each type of GD particles with mass fraction 0.01, 0.05, 0.10, and 0.15 were prepared via an easily scalable method-melt blending. The samples were subjected to the studies of electrical properties via broadband dielectric spectroscopy. The results indicated up to eight orders of magnitude improvement in the electrical conductivity and electrical permittivity of the most loaded nanocomposites, in reference to the neat PLA. Additionally, the influence of ash content on the electrical conductivity of the nanocomposites revealed that technologically less-demanding fillers, i.e., of higher ash content, were the most beneficial in the light of nanofiller dispersibility and the final properties.
采用两种不同灰分含量的石墨/金刚石(GD)颗粒制备新型导电聚乳酸(PLA)基纳米复合材料。通过易于扩展的方法——熔融共混,为每种类型的GD颗粒制备了质量分数分别为0.01、0.05、0.10和0.15的四个纳米复合材料样品。通过宽带介电谱对样品进行电学性能研究。结果表明,与纯PLA相比,负载量最高的纳米复合材料的电导率和电容率提高了多达八个数量级。此外,灰分含量对纳米复合材料电导率的影响表明,从纳米填料分散性和最终性能来看,技术要求较低的填料,即灰分含量较高的填料,最为有益。