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用于低成本钙钛矿太阳能电池的分子工程空穴传输材料。

Molecularly engineered hole-transport material for low-cost perovskite solar cells.

作者信息

Pashaei Babak, Bellani Sebastiano, Shahroosvand Hashem, Bonaccorso Francesco

机构信息

Group for Molecular Engineering of Advanced Functional Materials (GMA), Chemistry Department, University of Zanjan Zanjan Iran

Graphene Labs, Istituto Italiano di Tecnologia via Morego 30 16163 Genova Italy

出版信息

Chem Sci. 2020 Jan 13;11(9):2429-2439. doi: 10.1039/c9sc05694g.

DOI:10.1039/c9sc05694g
PMID:34084407
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8157471/
Abstract

Triphenylamine--phenyl-4-(phenyldiazenyl)aniline (TPA-AZO) is synthesized a facile CuI-catalyzed reaction and used as a hole transport material (HTM) in perovskite solar cells (PSCs), as an alternative to the expensive spiro-type molecular materials, including commercial 2,2',7,7'-tetrakis[,-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene (spiro-OMeTAD). Experimental and computational investigations reveal that the highest occupied molecular orbital (HOMO) level of TPA-AZO is deeper than that of spiro-OMeTAD, and optimally matches with the conduction band of the perovskite light absorber. The use of TPA-AZO as a HTM results in PSC prototypes with a power conversion efficiency (PCE) approaching that of the spiro-OMeTAD-based reference device (17.86% 19.07%). Moreover, the use of inexpensive starting reagents for the synthesis of TPA-AZO makes the latter a new affordable HTM for PSCs. In particular, the cost of 1 g of TPA-AZO ($22.76) is significantly lower compared to that of spiro-OMeTAD ($170-475). Overall, TPA-AZO-based HTMs are promising candidates for the implementation of viable PSCs in large-scale production.

摘要

三苯胺-苯基-4-(苯基重氮基)苯胺(TPA-AZO)通过一种简便的碘化亚铜催化反应合成，并用作钙钛矿太阳能电池(PSC)中的空穴传输材料(HTM)，作为包括商业用2,2',7,7'-四[,-二(4-甲氧基苯基)氨基]-9,9'-螺二芴(spiro-OMeTAD)在内的昂贵螺型分子材料的替代品。实验和计算研究表明，TPA-AZO的最高占据分子轨道(HOMO)能级比spiro-OMeTAD的更深，并且与钙钛矿光吸收体的导带最佳匹配。使用TPA-AZO作为HTM导致PSC原型的功率转换效率(PCE)接近基于spiro-OMeTAD的参考器件(17.86% 19.07%)。此外，使用廉价的起始试剂合成TPA-AZO使得后者成为一种新的、价格可承受的PSC空穴传输材料。特别是，1克TPA-AZO的成本(22.76美元)与spiro-OMeTAD的成本(170 - 475美元)相比显著更低。总体而言，基于TPA-AZO的空穴传输材料是大规模生产可行的PSC的有前途的候选材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/1fafea4ca210/c9sc05694g-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/4e5f907f3cea/c9sc05694g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/537d94810cf5/c9sc05694g-f2.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/ead0b8cdc222/c9sc05694g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/f337a865eb7f/c9sc05694g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/f2a0fbe94b7f/c9sc05694g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/a7d69b97b7db/c9sc05694g-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/3f47aea87203/c9sc05694g-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/1fafea4ca210/c9sc05694g-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/4e5f907f3cea/c9sc05694g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/537d94810cf5/c9sc05694g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/fed968bb0a12/c9sc05694g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/ead0b8cdc222/c9sc05694g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/f337a865eb7f/c9sc05694g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/f2a0fbe94b7f/c9sc05694g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/a7d69b97b7db/c9sc05694g-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/3f47aea87203/c9sc05694g-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8e7/8157471/1fafea4ca210/c9sc05694g-f9.jpg

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本文引用的文献

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Small. 2019 Jul;15(27):e1900854. doi: 10.1002/smll.201900854. Epub 2019 May 9.
2
Efficient, stable and scalable perovskite solar cells using poly(3-hexylthiophene).使用聚（3-己基噻吩）制备高效、稳定且可扩展的钙钛矿太阳能电池。
Nature. 2019 Mar;567(7749):511-515. doi: 10.1038/s41586-019-1036-3. Epub 2019 Mar 27.
3
Graphene-Induced Improvements of Perovskite Solar Cell Stability: Effects on Hot-Carriers.
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Chem Soc Rev. 2021 Nov 1;50(21):11870-11965. doi: 10.1039/d1cs00106j.
4
A new strategy for constructing a dispiro-based dopant-free hole-transporting material: spatial configuration of spiro-bifluorene changes from a perpendicular to parallel arrangement.一种构建基于双螺环的无掺杂空穴传输材料的新策略：螺双芴的空间构型从垂直排列变为平行排列。
Chem Sci. 2021 May 13;12(24):8548-8555. doi: 10.1039/d1sc01416a.
5
Low-Temperature Graphene-Based Paste for Large-Area Carbon Perovskite Solar Cells.用于大面积碳基钙钛矿太阳能电池的低温石墨烯基浆料
ACS Appl Mater Interfaces. 2021 May 19;13(19):22368-22380. doi: 10.1021/acsami.1c02626. Epub 2021 May 10.
石墨烯诱导钙钛矿太阳能电池稳定性的提升：对热载流子的影响。
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4
Hole transporting materials for perovskite solar cells: a chemical approach.钙钛矿太阳能电池用空穴传输材料：化学方法。
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7
Spinel CoO nanomaterials for efficient and stable large area carbon-based printed perovskite solar cells.尖晶石 CoO 纳米材料用于高效稳定的大面积基于碳的印刷钙钛矿太阳能电池。
Nanoscale. 2018 Feb 1;10(5):2341-2350. doi: 10.1039/c7nr08289d.
8
Perovskite solar cells with CuSCN hole extraction layers yield stabilized efficiencies greater than 20.钙钛矿太阳能电池采用 CuSCN 空穴萃取层，其稳定效率大于 20%。
Science. 2017 Nov 10;358(6364):768-771. doi: 10.1126/science.aam5655. Epub 2017 Sep 28.
9
Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells.碘化铯铅卤钙钛矿层中的碘化物管理以提高太阳能电池效率。
Science. 2017 Jun 30;356(6345):1376-1379. doi: 10.1126/science.aan2301.
10
One-Year stable perovskite solar cells by 2D/3D interface engineering.二维/三维界面工程实现稳定的钙钛矿太阳能电池一年
Nat Commun. 2017 Jun 1;8:15684. doi: 10.1038/ncomms15684.