Wu Ji Pei, Cheng Yi Chuan, Lu Lei, Wang Jun, Qiao Shan Bao
School of Chemistry & Environmental Engineering, Yancheng Teachers University, Yancheng, Jiangsu 224007, People's Republic of China.
Acta Crystallogr C Struct Chem. 2021 Jun 1;77(Pt 6):257-261. doi: 10.1107/S2053229621004642. Epub 2021 May 6.
A novel three-dimensional Cd coordination framework, namely, poly[{μ-bis[4-(2-methylimidazol-1-yl)phenyl] ether-κN:N}(μ-naphthalene-1,4-dicarboxylato-κO:O,O)cadmium(II)], [Cd(CHO)(CHNO)] or [Cd(1,4-NDC)(BMIOPE)], where 1,4-HNDC is naphthalene-1,4-dicarboxylic acid and BMIOPE is bis[4-(2-methylimidazol-1-yl)phenyl] ether, has been prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermogravimetric analysis. The compound displays a novel fourfold interpenetrating diamond-like network. In addition, it not only shows a strong fluorescence emission in the solid state, but also exhibits excellent photocatalytic activity for the degradation of methylene blue (MB) at room temperature.
一种新型的三维镉配位框架，即聚[{μ-双[4-(2-甲基咪唑-1-基)苯基]醚-κN:N}(μ-萘-1,4-二羧基-κO:O,O)镉(II)]，[Cd(CHO)(CHNO)] 或 [Cd(1,4-NDC)(BMIOPE)]，其中1,4-HNDC是萘-1,4-二羧酸，BMIOPE是双[4-(2-甲基咪唑-1-基)苯基]醚，已通过单晶X射线衍射、元素分析、红外光谱和热重分析进行了制备和表征。该化合物展示出一种新型的四重互穿类金刚石网络。此外，它不仅在固态下表现出强烈的荧光发射，而且在室温下对亚甲基蓝（MB）的降解表现出优异的光催化活性。
