Chen Hui Ru
Department of Pharmaceutical Technology and Biological Engineering, Changzhou Institute of Engineering Technology, Changzhou 213164, People's Republic of China.
Acta Crystallogr C Struct Chem. 2021 Nov 1;77(Pt 11):734-739. doi: 10.1107/S2053229621010639. Epub 2021 Oct 27.
A novel three-dimensional (3D) Cd coordination polymer, namely, poly[μ-4,4'-bis(2-methylimidazol-1-yl)-[1,1'-biphenyl]cadmium(II)], [Cd(CHO)(CHN)] or [Cd(MIP)(4,4'-BMIBP)], (I), was synthesized by the hydrothermal method using 5-methylisophthalic acid (HMIP), 4,4'-bis(2-methylimidazol-1-yl)-[1,1'-biphenyl] (4,4'-BMIBP) and Cd(NO)·6HO, and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermogravimetric analysis. Compound (I) exhibits a novel fivefold interpenetrating 3D diamondoid framework. Additionally, it shows fluorescence emission in the solid state and promising photocatalytic activities for the degradation of methylene blue (MB) in water at room temperature.
一种新型的三维（3D）镉配位聚合物，即聚[μ-4,4'-双（2-甲基咪唑-1-基）-[1,1'-联苯]·6HO合成，并通过单晶X射线衍射、元素分析、红外光谱和热重分析进行表征。化合物（I）呈现出一种新型的五重互穿三维类金刚石骨架。此外，它在固态下表现出荧光发射，并且在室温下对水中亚甲基蓝（MB）的降解具有良好的光催化活性。
