Sumino Shuhei, Matsumoto Fukashi, Iwai Toshiyuki, Ito Takatoshi
Research Division of Organic Materials, Osaka Research Institute of Industrial Science and Technology (ORIST), 1-6-50, Morinomiya, Osaka 536-8553, Japan.
J Org Chem. 2021 Jun 18;86(12):8500-8507. doi: 10.1021/acs.joc.1c00593. Epub 2021 Jun 7.
This work describes the synthesis of PCBM ([6,6]-phenyl-C-butyric acid methyl ester) derivatives and other methanofullerene derivatives via generation of fullerene radical anions under photoirradiation and controlled by photoswitching, without preparation, a strong reducing agent, or precise control of the reaction conditions.
这项工作描述了通过光照射下富勒烯自由基阴离子的生成，并由光开关控制，在无需制备强还原剂或精确控制反应条件的情况下，合成PCBM（[6,6]-苯基-C-丁酸甲酯）衍生物和其他甲烷富勒烯衍生物的方法。
