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光催化领域中助催化剂的类型、制备及其应用

Cocatalysts from types, preparation to applications in the field of photocatalysis.

作者信息

Zhao Gang, Xu Xijin

机构信息

Laboratory of Functional Micro-nano Material and Device, School of Physics and Technology, University of Jinan, Jinan, Shandong, P. R. China.

出版信息

Nanoscale. 2021 Jun 24;13(24):10649-10667. doi: 10.1039/d1nr02464g.

Abstract

With the rapid development of society, the burden of energy and the environment is becoming more and more serious. Photocatalytic hydrogen production, the photosynthesis of organic fuel, and the photodegradation of pollutants are three effective ways to reduce these burdens using semiconductor photocatalysts. To improve the reaction efficiency of photocatalysts, a small amount of cocatalyst is often added when photocatalysts participate in the synthesis or decomposition reaction. The addition of this small amount of cocatalyst is like a finishing touch, significantly increasing the activity of the photocatalysts. However, in our common study of photocatalysis, we often pay attention to the study of photocatalysts but ignore the study of cocatalysts. Herein, we summarize the recent application research on cocatalysts in the field of photocatalysis, starting from the types, preparation methods, and reaction mechanisms among others, to remind researchers of the matters needing attention when using cocatalysts.

摘要

随着社会的快速发展,能源和环境负担日益加重。光催化制氢、有机燃料的光合作用以及污染物的光降解是利用半导体光催化剂减轻这些负担的三种有效途径。为了提高光催化剂的反应效率,在光催化剂参与合成或分解反应时,常添加少量助催化剂。这少量助催化剂的添加犹如画龙点睛之笔,显著提高了光催化剂的活性。然而,在我们对光催化的常规研究中,往往注重光催化剂的研究而忽略了对助催化剂的研究。在此,我们从类型、制备方法、反应机理等方面总结了助催化剂在光催化领域的近期应用研究,以提醒研究人员在使用助催化剂时需要注意的事项。

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