Zang Xiaobei, Wang Jiali, Qin Yijiang, Wang Teng, He Chengpeng, Shao Qingguo, Zhu Hongwei, Cao Ning
School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, 266580, People's Republic of China.
School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, People's Republic of China.
Nanomicro Lett. 2020 Mar 20;12(1):77. doi: 10.1007/s40820-020-0415-5.
TiCT, a novel two-dimensional layer material, is widely used as electrode materials of supercapacitor due to its good metal conductivity, redox reaction active surface, and so on. However, there are many challenges to be addressed which impede TiCT obtaining the ideal specific capacitance, such as restacking, re-crushing, and oxidation of titanium. Recently, many advances have been proposed to enhance capacitance performance of TiCT. In this review, recent strategies for improving specific capacitance are summarized and compared, for example, film formation, surface modification, and composite method. Furthermore, in order to comprehend the mechanism of those efforts, this review analyzes the energy storage performance in different electrolytes and influencing factors. This review is expected to predict redouble research direction of TiCT materials in supercapacitors.
TiCT是一种新型二维层状材料,因其良好的金属导电性、氧化还原反应活性表面等,被广泛用作超级电容器的电极材料。然而,要使TiCT获得理想的比电容仍有许多挑战需要解决,比如重新堆叠、再次粉碎以及钛的氧化等问题。最近,人们提出了许多提高TiCT电容性能的进展。在这篇综述中,总结并比较了近期提高比电容的策略,例如成膜、表面改性和复合方法。此外,为了理解这些努力的机制,本综述分析了在不同电解质中的储能性能及影响因素。预计本综述将为TiCT材料在超级电容器中的研究方向提供双重预测。