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通过TiCT MXene和CoMoO纳米颗粒实现超级电容器中协同电荷存储增强

Synergistic Charge Storage Enhancement in Supercapacitors via TiCT MXene and CoMoO Nanoparticles.

作者信息

Young Christine, Wu An-Yi, Li Ri-Yu

机构信息

Functional Nanoporous Materials Laboratory, Department of Chemical and Materials Engineering, National Yunlin University of Science and Technology, Yunlin 640, Taiwan.

出版信息

Micromachines (Basel). 2024 Feb 1;15(2):234. doi: 10.3390/mi15020234.

Abstract

MXene has emerged as a highly promising two-dimensional (2D) layered material with inherent advantages as an electrode material, such as a high electrical conductivity and spacious layer distances conducive to efficient ion transport. Despite these merits, the practical implementation faces challenges due to MXene's low theoretical capacitance and issues related to restacking. In order to overcome these limitations, we undertook a strategic approach by integrating TiCT MXene with cobalt molybdate (CoMoO) nanoparticles. The CoMoO nanoparticles bring to the table rich redox activity, high theoretical capacitance, and exceptional catalytic properties. Employing a facile hydrothermal method, we synthesized CoMoO/TiCT heterostructures, leveraging urea as a size-controlling agent for the CoMoO precursors. This innovative heterostructure design utilizes TiCT MXene as a spacer, effectively mitigating excessive agglomeration, while CoMoO contributes its enhanced redox reaction capabilities. The resulting CoMoO/TCT MXene hybrid material exhibited 698 F g at a scan rate of 5 mV s, surpassing that of the individual pristine TiCT MXene (1.7 F g) and CoMoO materials (501 F g). This integration presents a promising avenue for optimizing MXene-based electrode materials, addressing challenges and unlocking their full potential in various applications.

摘要

MXene已成为一种极具前景的二维(2D)层状材料,作为电极材料具有固有优势,如高电导率和有利于高效离子传输的宽敞层间距。尽管有这些优点,但由于MXene的理论电容较低以及与重新堆叠相关的问题,其实际应用面临挑战。为了克服这些限制,我们采取了一种策略性方法,将TiCT MXene与钼酸钴(CoMoO)纳米颗粒集成。CoMoO纳米颗粒具有丰富的氧化还原活性、高理论电容和出色的催化性能。我们采用简便的水热法合成了CoMoO/TiCT异质结构,利用尿素作为CoMoO前驱体的尺寸控制剂。这种创新的异质结构设计利用TiCT MXene作为间隔层,有效减轻过度团聚,而CoMoO则贡献其增强的氧化还原反应能力。所得的CoMoO/TCT MXene混合材料在扫描速率为5 mV s时表现出698 F g的电容,超过了单独的原始TiCT MXene(1.7 F g)和CoMoO材料(501 F g)。这种集成展示了一条优化基于MXene的电极材料的有前途的途径,解决了挑战并释放了它们在各种应用中的全部潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75d/10893255/1af9febd16c8/micromachines-15-00234-g001.jpg

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