Institute of Geological Sciences, Jagiellonian University, Gronostajowa 3a, 30-387 Kraków, Poland.
Centre for Environmental Education, Jagiellonian University, Gronostajowa 5, 30-387 Kraków, Poland.
Sci Total Environ. 2021 Oct 15;791:148313. doi: 10.1016/j.scitotenv.2021.148313. Epub 2021 Jun 6.
Incinerations residues from different types of materials (sewage sludge incineration ash and municipal waste incineration ashes) can either be by-products used in industry, or can pose a serious environmental problem related to their composition and the presence of potentially hazardous elements. State regulations and standards indicate whether material is inert, non-hazardous or hazardous. These standards, however, do not provide a complete overview on the leaching behavior of potentially hazardous elements in the environment. This study presents the result of batch experiment performed in accordance with the PN-EN 12457-2 (2006) and PN-EN 12457-4 (2006) standards. The results indicated that the leachability of elements is strongly dependent on the mineral composition of the waste product (the concentration and composition of soluble phase), the chemical composition (the mobility of hazardous elements and their affinity to soluble minerals), and the pH. To ensure environmental safety a thorough characterization of the waste is required followed by qualitative assignment to a particular waste type based on available guidance. Furthermore, to avoid leaching of potentially harmful elements into soils or surface water, it is also paramount to perform environmental impact assessment of wastes used as by-product in industry e.g., as building or road construction materials (aggregate) and fertilizers.
来自不同类型材料(污水污泥焚烧灰和城市垃圾焚烧灰)的焚烧残余物可以是工业用的副产品,也可能因其成分和潜在危险元素的存在而构成严重的环境问题。国家法规和标准表明材料是惰性的、无害的还是危险的。然而,这些标准并没有全面概述潜在危险元素在环境中的浸出行为。本研究根据 PN-EN 12457-2(2006)和 PN-EN 12457-4(2006)标准进行了批处理实验,结果表明,元素的浸出率强烈依赖于废物的矿物组成(可溶性相的浓度和组成)、化学成分(危险元素的迁移性及其对可溶性矿物的亲和力)和 pH 值。为了确保环境安全,需要对废物进行彻底的特性描述,并根据现有指南对其进行定性分配到特定的废物类型。此外,为了避免潜在有害元素浸出到土壤或地表水,还必须对工业副产品(例如建筑或道路建筑材料(骨料)和肥料)进行环境影响评估。