Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China.
Institute for Mechanical Process Engineering and Mechanics, Karlsruhe Institute of Technology, Karlsruhe, 76131, Germany.
Small. 2021 Oct;17(40):e2008079. doi: 10.1002/smll.202008079. Epub 2021 Jun 17.
Biomass-derived carbon materials (BCMs) are encountering the most flourishing moment because of their versatile properties and wide potential applications. Numerous BCMs, including 0D carbon spheres and dots, 1D carbon fibers and tubes, 2D carbon sheets, 3D carbon aerogel, and hierarchical carbon materials have been prepared. At the same time, their structure-property relationship and applications have been widely studied. This paper aims to present a review on the recent advances in the controllable preparation and potential applications of BCMs, providing a reference for future work. First, the chemical compositions of typical biomass and their thermal degradation mechanisms are presented. Then, the typical preparation methods of BCMs are summarized and the relevant structural management rules are discussed. Besides, the strategies for improving the structural diversity of BCMs are also presented and discussed. Furthermore, the applications of BCMs in energy, sensing, environment, and other areas are reviewed. Finally, the remaining challenges and opportunities in the field of BCMs are discussed.
生物量衍生碳材料(BCMs)因其多功能特性和广泛的潜在应用而迎来了最繁荣的时刻。已经制备了许多 BCM,包括 0D 碳球和点、1D 碳纤维和管、2D 碳片、3D 碳气凝胶和分级碳材料。同时,它们的结构-性能关系和应用已经得到了广泛的研究。本文旨在综述 BCMs 的可控制备和潜在应用的最新进展,为未来的工作提供参考。首先,介绍了典型生物质的化学成分及其热降解机制。然后,总结了 BCMs 的典型制备方法,并讨论了相关的结构管理规则。此外,还提出并讨论了提高 BCMs 结构多样性的策略。此外,还综述了 BCMs 在能源、传感、环境等领域的应用。最后,讨论了 BCMs 领域的剩余挑战和机遇。