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利用适应性嗜酸细菌从废弃OLED触摸屏中生物浸出关键金属。

Bioleaching of critical metals from waste OLED touch screens using adapted acidophilic bacteria.

作者信息

Pourhossein Fatemeh, Rezaei Omid, Mousavi Seyyed Mohammad, Beolchini Francesca

机构信息

Biotechnology Group, Chemical Engineering Department, Tarbiat Modares University, Tehran, Iran.

Department of Life and Environmental Sciences, Università Politecnica delle Marche, Ancona, Italy.

出版信息

J Environ Health Sci Eng. 2021 May 4;19(1):893-906. doi: 10.1007/s40201-021-00657-2. eCollection 2021 Jun.

Abstract

The mobile phone is a fast-growing E-waste stream that includes hazardous substances and valuable metals. Smartphone touch screens (SPTS) contain a considerable amount of critical metals, such as indium and strontium that can be recovered from end of life devices as a secondary resource. Bioleaching is an emerging and environmentally friendly method for metal recovery from electronic waste. In the present study, bioleaching was assessed for the extraction of indium and strontium from organic light emitting diode type smartphone touch screens. A statistical approach based on the response surface methodology was successfully applied. The effects of influential variables: pH, ferrous sulfate, elemental sulfur, and solid content and their interactions on indium and strontium recovery using adapted were evaluated. Under optimum conditions (ferrous sulfate: 13.0 g/L; solid content; 3.0 g/L; elemental sulfur: 5.6 g/L; and initial pH of 1.1), a complete indium extraction was observed, with a concentration in solution of about 200 mg/L indium. As concerns strontium, a 5% extraction efficiency was observed, which, even if quite low, resulted in a relatively high strontium concentration in solution, around 3000 mg/L, due to its high content in the solid (2%). This work opens new perspectives in the application of clean technologies for the extraction of valuable metals, such as indium and strontium from smartphone screens.

摘要

手机是一种快速增长的电子垃圾流,其中包含有害物质和贵重金属。智能手机触摸屏(SPTS)含有大量关键金属,如铟和锶,这些金属可从报废设备中回收作为二次资源。生物浸出是一种从电子废物中回收金属的新兴且环保的方法。在本研究中,评估了生物浸出法从有机发光二极管型智能手机触摸屏中提取铟和锶的效果。成功应用了基于响应面法的统计方法。评估了影响变量(pH值、硫酸亚铁、元素硫和固体含量)及其相互作用对使用改良方法回收铟和锶的影响。在最佳条件下(硫酸亚铁:13.0 g/L;固体含量:3.0 g/L;元素硫:5.6 g/L;初始pH值为1.1),观察到铟完全被提取,溶液中铟的浓度约为200 mg/L。至于锶,观察到提取效率为5%,尽管相当低,但由于其在固体中的含量较高(2%),溶液中的锶浓度相对较高,约为3000 mg/L。这项工作为应用清洁技术从智能手机屏幕中提取铟和锶等贵重金属开辟了新的前景。

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