超短 HH 分子间距离在固态超分子体系中。
Ultrashort HH intermolecular distance in a supramolecular system in the solid state.
机构信息
Univ Rennes, CNRS, ISCR-UMR6226, Rennes F-35000, France.
Department of Quimica, Universitat de les Illes Balears, Crta. De Valldemossa km 7.5, Palma de Mallorca 07122, Baleares, Spain.
出版信息
Chem Commun (Camb). 2021 Jul 20;57(58):7112-7115. doi: 10.1039/d1cc02143e.
PMID:34179902
Abstract
Herein we report experimental evidence for the shortest intermolecular distance reported for two electronically-different hydrogen atoms in the solid state. The Hδ+Hδ- non-covalent interaction was studied using theoretical calculations indicating that electrostatic and dispersion forces are of paramount importance.
摘要
在此，我们报告了在固态中报道的两个电子不同的氢原子之间最短的分子间距离的实验证据。使用理论计算研究了 Hδ+Hδ-非共价相互作用，表明静电和色散力至关重要。
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