N：一种作为高能量密度材料的新型同配多氮离子
N : A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material.
作者信息
Christe Karl O, Wilson William W, Sheehy Jeffrey A, Boatz Jerry A
机构信息
Propulsion Sciences and Advanced Concepts Division, Air Force Research Laboratory (AFRL/PRS), Edwards Air Force Base, CA 93524 (USA), Fax: (+1) 661-275-5471 (and) Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, CA 90089 (USA).
出版信息
Angew Chem Int Ed Engl. 1999 Jul 12;38(13-14):2004-2009. doi: 10.1002/(SICI)1521-3773(19990712)38:13/14<2004::AID-ANIE2004>3.0.CO;2-7.
Only the third known example of a homoleptic polynitrogen species besides N and N , the N ion possesses surprising stability and can be isolated on a macroscopic scale as its AsF salt. The assigment of the C-symmetric structure (shown schematically) predicted by calculations was supported by IR and Raman as well as N and N NMR spectroscopic studies of the isotopically labeled product.
作为除N₂和N₃⁺之外第三种已知的同配多氮物种，N₅⁺离子具有惊人的稳定性，并且可以作为其AsF₆盐在宏观尺度上分离出来。计算预测的C对称结构（示意图所示）通过红外光谱、拉曼光谱以及对同位素标记产物的¹⁵N和¹⁴N核磁共振光谱研究得到了证实。
Zotero 插件