通过分子层外延实现的有机量子受限结构

Organic Quantum-Confined Structures through Molecular Layer Epitaxy.

作者信息

Burtman Vladimir, Zelichenok Alexander, Yitzchaik Shlomo

机构信息

Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904 (Israel), Fax: (+972) 2-6585319.

出版信息

Angew Chem Int Ed Engl. 1999 Jul 12;38(13-14):2041-2045. doi: 10.1002/(SICI)1521-3773(19990712)38:13/14<2041::AID-ANIE2041>3.0.CO;2-H.

DOI:10.1002/(SICI)1521-3773(19990712)38:13/14<2041::AID-ANIE2041>3.0.CO;2-H

PMID:34182689

Abstract

A new approach, molecular layer epitaxy (MLE), is introduced for the vapor-phase assembly of organic multilayers integrated in molecular electronic devices. The MLE approach uses carrier gas assisted epitaxial deposition, covalent bonding, and horizontal π stacking in a pulsed mode for layer-by-layer growth of 1,8:4,5-naphthalenetetracarbodiimide with a hexamethylene spacer (shown schematically).

摘要

一种新方法——分子层外延（MLE）被引入用于分子电子器件中集成的有机多层膜的气相组装。MLE方法采用载气辅助外延沉积、共价键合以及脉冲模式下的水平π堆积，用于逐层生长带有六亚甲基间隔基的1,8:4,5-萘四碳二亚胺（如图所示）。