Khalil-Cruz Laila E, Liu Peiren, Huang Feihe, Khashab Niveen M
Smart Hybrid Materials Laboratory (SHMs), Advanced Membranes and Porous Materials Center, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia.
State Key Laboratory of Chemical Engineering, Center for Chemistry of High- Performance & Novel Materials, Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China.
ACS Appl Mater Interfaces. 2021 Jul 14;13(27):31337-31354. doi: 10.1021/acsami.1c05798. Epub 2021 Jun 29.
The construction of smart nanomaterials from host macrocycles that are responsive to specific stimuli has gained significant attention in recent years. The application of pillar[]arenes has been of particular interest given their ease of functionalization and tunability of the intrinsic cavity electronic properties that allows them to encapsulate a great variety of guests and complex with metal ions with high selectivity via noncovalent interactions, endowing them with captivating properties and functions. Herein, we present the most recent advances in the design and functionalization of pillar[]arene-based smart nanomaterials, and their applications for sensing, catalysis, drug delivery, and artificial transmembrane channels.
近年来，由对特定刺激有响应的主体大环构建智能纳米材料受到了广泛关注。柱芳烃的应用尤其令人感兴趣，因为它们易于功能化，且其固有腔内电子性质具有可调性，这使得它们能够通过非共价相互作用封装多种客体并与金属离子高选择性地络合，从而赋予它们迷人的性质和功能。在此，我们展示了基于柱芳烃的智能纳米材料在设计和功能化方面的最新进展，以及它们在传感、催化、药物递送和人工跨膜通道方面的应用。
