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采用热压技术和 Mg 空间占位剂制备多孔 Ti6Al4V 合金,用于硬组织生物医学应用。

Fabrication of porous-Ti6Al4V alloy by using hot pressing technique and Mg space holder for hard-tissue biomedical applications.

机构信息

Department of Metallurgical and Materials Engineering, Faculty of Engineering, Munzur University, Tunceli, Turkey.

Munzur University Rare Earth Elements Application and Research Center, Tunceli, Turkey.

出版信息

J Mater Sci Mater Med. 2021 Jun 30;32(7):80. doi: 10.1007/s10856-021-06546-2.

Abstract

Porous-Ti6Al4V (P-Ti6Al4V) alloys were produced using the hot pressing and spacer methods for hard tissue biomedical applications and in particular, the effects of porosity on the mechanical and morphological properties of the structures were investigated. P-Ti6Al4V structures having the homogeneously distributed porosities at 41.08, 52.37 and 64.10% were fabricated by adding 40, 50 and 60% spherical magnesium (Mg) powder with 350 μm particle sizes in average as spacers and evaporating magnesium via the atmosphere-controlled sintering. The obtained porous structures were characterized by SEM, XRD and EDS. Furthermore, the strength and elastic modulus were evaluated by performing compression tests. Elastic modulus and densities were found to be 40-171 MPa, 2-5 GPa and 1.59-2.61, respectively and these values have been shown to decrease with an increase in porosity. The achieved density and mechanical property values, in particular, elastic modulus are close to human bone and within acceptable ranges for with biomedical application purposes. In addition, it was also found out from the analysis of produced P-Ti6Al4V that macropores were responsible for mechanical anisotropy contributed to formation of homogeneous and inter-connected open pores.

摘要

多孔 Ti6Al4V(P-Ti6Al4V)合金采用热压和隔垫法生产,用于硬组织生物医学应用,特别是研究了孔隙率对结构的机械和形态特性的影响。通过添加平均粒径为 350μm 的 40%、50%和 60%球形镁(Mg)粉末作为隔垫,并通过气氛控制烧结蒸发镁,制备出具有均匀分布的 41.08%、52.37%和 64.10%孔隙率的 P-Ti6Al4V 结构。通过 SEM、XRD 和 EDS 对获得的多孔结构进行了表征。此外,通过压缩试验评估了强度和弹性模量。发现弹性模量和密度分别为 40-171MPa、2-5GPa 和 1.59-2.61,这些值随着孔隙率的增加而降低。所获得的密度和机械性能值,特别是弹性模量,与人骨接近,并且在生物医学应用目的的可接受范围内。此外,通过对生产的 P-Ti6Al4V 的分析还发现,大孔是导致机械各向异性的原因,有助于形成均匀和相互连通的开孔。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60ce/8245386/360b83cf2900/10856_2021_6546_Fig1_HTML.jpg

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