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基于Ti-42Nb的新型增材制造植入材料的力学性能

Mechanical Properties of a Newly Additive Manufactured Implant Material Based on Ti-42Nb.

作者信息

Schulze Christian, Weinmann Markus, Schweigel Christoph, Keßler Olaf, Bader Rainer

机构信息

Biomechanics and Implant Technology Research Laboratory (FORBIOMIT), Department of Orthopaedics, University Medicine Rostock, Doberaner Straße 142, 18057 Rostock, Germany.

H.C. Starck Tantalum and Niobium GmbH, Im Schleeke 78-91, 38642 Goslar, Germany.

出版信息

Materials (Basel). 2018 Jan 13;11(1):124. doi: 10.3390/ma11010124.

Abstract

The application of Ti-6Al-4V alloy or commercially pure titanium for additive manufacturing enables the fabrication of complex structural implants and patient-specific implant geometries. However, the difference in Young's modulus of α + β-phase Ti alloys compared to the human bone promotes stress-shielding effects in the implant-bone interphase. The aim of the present study is the mechanical characterization of a new pre-alloyed β-phase Ti-42Nb alloy for application in additive manufacturing. The present investigation focuses on the mechanical properties of SLM-printed Ti-42Nb alloy in tensile and compression tests. In addition, the raw Ti-42Nb powder, the microstructure of the specimens prior to and after compression tests, as well as the fracture occurring in tensile tests are characterized by means of the SEM/EDX analysis. The Ti-42Nb raw powder exhibits a dendrite-like Ti-structure, which is melted layer-by-layer into a microstructure with a very homogeneous distribution of Nb and Ti during the SLM process. Tensile tests display Young's modulus of 60.51 ± 3.92 GPa and an ultimate tensile strength of 683.17 ± 16.67 MPa, whereas, under a compressive load, a compressive strength of 1330.74 ± 53.45 MPa is observed. The combination of high mechanical strength and low elastic modulus makes Ti-42Nb an interesting material for orthopedic and dental implants. The spherical shape of the pre-alloyed material additionally allows for application in metal 3D printing, enabling the fabrication of patient-specific structural implants.

摘要

将Ti-6Al-4V合金或工业纯钛应用于增材制造,能够制造复杂结构的植入物以及根据患者定制的植入物几何形状。然而,α + β相钛合金与人体骨骼相比,杨氏模量存在差异,这会在植入物与骨骼的界面处产生应力屏蔽效应。本研究的目的是对一种用于增材制造的新型预合金化β相Ti-42Nb合金进行力学表征。本研究聚焦于选择性激光熔化(SLM)打印的Ti-42Nb合金在拉伸和压缩试验中的力学性能。此外,通过扫描电子显微镜/能谱分析(SEM/EDX)对原始Ti-42Nb粉末、压缩试验前后试样的微观结构以及拉伸试验中出现的断裂进行表征。Ti-42Nb原始粉末呈现出树枝状的钛结构,在SLM过程中,该结构逐层熔化,形成Nb和Ti分布非常均匀的微观结构。拉伸试验显示杨氏模量为60.51±3.92 GPa,极限抗拉强度为683.17±1—6.67 MPa,而在压缩载荷下,观察到抗压强度为1330.74±53.45 MPa。高机械强度和低弹性模量的结合,使得Ti-42Nb成为用于骨科和牙科植入物的一种有吸引力的材料。预合金化材料的球形形状还允许其应用于金属3D打印,从而能够制造根据患者定制的结构植入物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7771/5793622/f70ecc1e465d/materials-11-00124-g001.jpg

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