Sun Jie, Sun Baoguo, Ren Fazheng, Chen Haitao, Zhang Ning, Zhang Yuyu, Zhang Huiying
Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing 100048, China.
Beijing Advanced Innovation Center for Food Nutrition and Human Health, College of Food Science & Nutritional Engineering, China Agricultural University, Beijing 100083, China.
Foods. 2021 Jun 4;10(6):1292. doi: 10.3390/foods10061292.
Flavor stability of fried pepper oil was investigated during 30 days of storage. Variation trends of key volatile flavor compounds in fried pepper oil induced by ultraviolet (UV) irradiation and oxygen (O) exposure were compared using GC-MS and chiral GC-MS analysis. Chirality analysis showed that conversion of (S)-(-)-limonene to (R)-(+)-limonene form was observed during storage. The storage conditions did not change the configuration of linalool, linalool oxide, or carvone. Quantitative analysis showed that the concentrations of linalool, limonene, 1,8-cineole, β-myrcene, and β-ocimene decreased dramatically during storage, whereas carvone, (E)-2-heptenal, and linalool oxide showed an increasing trend during storage. The loss rate of limonene and linalool exhibited the highest under combined UV and O condition, which played an important role for the aroma attenuation of pepper oil. This result will benefit the storage of pepper oil and based on pepper oil aromatic products.
研究了花椒油在30天储存期内的风味稳定性。采用气相色谱-质谱联用(GC-MS)和手性气相色谱-质谱联用分析方法,比较了紫外线(UV)照射和氧气(O)暴露对花椒油中关键挥发性风味化合物的影响趋势。手性分析表明,储存过程中观察到(S)-(-)-柠檬烯向(R)-(+)-柠檬烯形式的转化。储存条件未改变芳樟醇、氧化芳樟醇或香芹酮的构型。定量分析表明,储存期间芳樟醇、柠檬烯、1,8-桉叶素、β-月桂烯和β-罗勒烯的浓度显著降低,而香芹酮、(E)-2-庚烯醛和氧化芳樟醇则呈上升趋势。在UV和O联合作用下,柠檬烯和芳樟醇的损失率最高,这对花椒油的香气衰减起重要作用。该结果将有助于花椒油及以花椒油为原料的芳香产品的储存。