Transparent, Conductive Hydrogels with High Mechanical Strength and Toughness.

Transparent, conductive hydrogels with good mechanical strength and toughness are in great demand of the fields of biomedical and future wearable smart electronics. We reported a carboxymethyl chitosan (CMCS)-calcium chloride (CaCl)/polyacrylamide (PAAm)/poly(N-methylol acrylamide (PNMA) transparent, tough and conductive hydrogel containing a bi-physical crosslinking network through in situ free radical polymerization. It showed excellent light transmittance (>90%), excellent toughness (10.72 MJ/m), good tensile strength (at break, 2.65 MPa), breaking strain (707%), and high elastic modulus (0.30 MPa). The strain sensing performance is found with high sensitivity (maximum gauge factor 9.18, 0.5% detection limit), wide strain response range, fast response and recovery time, nearly zero hysteresis and good repeatability. This study extends the transparent, tough, conductive hydrogels to provide body-surface wearable devices that can accurately and repeatedly monitor the movement of body joints, including the movements of wrists, elbows and knee joints. This study provided a broad development potential for tough, transparent and conductive hydrogels as body-surface intelligent health monitoring systems and implantable soft electronics.