Liu Fengguo, Su Ning, Guan Renguo
School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China.
School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110004, China.
Materials (Basel). 2021 Jun 9;14(12):3163. doi: 10.3390/ma14123163.
Multilayer reduced graphene oxide (mrGO) was chemically modified by electroless plating of copper on surface to form mrGO-Cu. The scanning electron microscope (SEM) and transmission electron microscope (TEM) analysis revealed that nano-Cu particles were uniformly dispersed on the surface of mrGO. The mrGO-Cu powders were further utilized as reinforcements for aluminum (Al) matrix and the mrGO-Cu/Al composite was successfully fabricated through clad rolling of milled powder. The tribological properties of the mrGO-Cu/Al composites were explored. The tribological results show that the mrGO-Cu could reduce the friction coefficient and wear loss of mrGO-Cu/Al composites, since the mrGO-Cu participated in lubricating processes due to the formation of a transfer layer on the contact surface. Furthermore, it is found that the composition of mrGO-Cu could significantly influence the tribological properties of the mrGO-Cu/Al composites. The composites with 4% of mrGO-Cu for composites exhibited the best tribological behavior, which transformed from adhesive wear to abrasive wear, due to the formation of a graphite lubricating film.
通过在多层还原氧化石墨烯(mrGO)表面进行化学镀铜对其进行改性,以形成mrGO-Cu。扫描电子显微镜(SEM)和透射电子显微镜(TEM)分析表明,纳米铜颗粒均匀分散在mrGO表面。mrGO-Cu粉末进一步用作铝(Al)基的增强材料,并通过研磨粉末的包覆轧制成功制备了mrGO-Cu/Al复合材料。研究了mrGO-Cu/Al复合材料的摩擦学性能。摩擦学结果表明,mrGO-Cu可以降低mrGO-Cu/Al复合材料的摩擦系数和磨损损失,因为mrGO-Cu由于在接触表面形成转移层而参与润滑过程。此外,发现mrGO-Cu的组成会显著影响mrGO-Cu/Al复合材料的摩擦学性能。含4% mrGO-Cu的复合材料表现出最佳的摩擦学行为,由于形成了石墨润滑膜,其磨损机制从粘着磨损转变为磨粒磨损。