Abu Hassan Shaari Helyati, Ramli Muhammad Mahyiddin, Mohtar Mohd Nazim, Abdul Rahman Norizah, Ahmad Azizan
Institute of Advanced Technology, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia.
Faculty of Applied Sciences, Universiti Teknologi MARA Perlis Branch, Arau Campus, Arau 02600, Perlis, Malaysia.
Polymers (Basel). 2021 Jun 11;13(12):1939. doi: 10.3390/polym13121939.
Poly(methyl methacrylate) (PMMA) is a lightweight insulating polymer that possesses good mechanical stability. On the other hand, polyaniline (PANi) is one of the most favorable conducting materials to be used, as it is easily synthesized, cost-effective, and has good conductivity. However, most organic solvents have restricted potential applications due to poor mechanical properties and dispersibility. Compared to PANi, PMMA has more outstanding physical and chemical properties, such as good dimensional stability and better molecular interactions between the monomers. To date, many research studies have focused on incorporating PANi into PMMA. In this review, the properties and suitability of PANi as a conducting material are briefly reviewed. The major parts of this paper reviewed different approaches to incorporating PANi into PMMA, as well as evaluating the modifications to improve its conductivity. Finally, the polymerization condition to prepare PMMA/PANi copolymer to improve its conductivity is also discussed.
聚甲基丙烯酸甲酯(PMMA)是一种轻质绝缘聚合物,具有良好的机械稳定性。另一方面,聚苯胺(PANi)是最适合使用的导电材料之一,因为它易于合成、成本效益高且具有良好的导电性。然而,大多数有机溶剂由于机械性能和分散性较差而限制了其潜在应用。与PANi相比,PMMA具有更优异的物理和化学性质,如良好的尺寸稳定性以及单体之间更好的分子相互作用。迄今为止,许多研究都集中在将PANi掺入PMMA中。在本综述中,简要回顾了PANi作为导电材料的性质和适用性。本文的主要部分回顾了将PANi掺入PMMA的不同方法,以及评估改善其导电性的改性方法。最后,还讨论了制备PMMA/PANi共聚物以提高其导电性的聚合条件。