Faculty of Technology, Fibre and Particle Engineering Research Unit, University of Oulu, PO Box 4300 90014, Finland.
Faculty of Technology, Fibre and Particle Engineering Research Unit, University of Oulu, PO Box 4300 90014, Finland.
Waste Manag. 2021 Jul 15;131:323-330. doi: 10.1016/j.wasman.2021.06.022. Epub 2021 Jul 1.
Despite mineral wool waste is only a small fraction of total construction and demolition waste (CDW) by mass, it requires large transportation and landfilling capacities due to its low bulk density, and its utilization remains low compared to other CDW types. It is essential to understand the physical and chemical properties of this waste fraction in order to utilize it, e.g. as fiber reinforcement in composites or as supplementary cementitious material. Here, we provide a chemical and physical characterization of 15 glass wool and 12 stone wool samples of different ages collected from various locations across Europe. In addition, the chemical compositions of 61 glass and stone wool samples obtained from the literature are presented. Glass wool samples show little variation in their chemical composition, which resembles the composition of typical soda-lime silicate glass. Stone wool presents a composition similar to basaltic glass but with variability between samples in terms of calcium, magnesium, and iron content. Potentially toxic elements, such as Cr, Ba, and Ni, are present in mineral wools, but in low concentrations (<0.2%). Both wool types contain organic resin, which may decompose into smaller molecular fragments and ammonia upon heating or contact with alkaline solution. Mineral wool wastes have relatively similar length and width distributions, despite the age and type of the mineral wool. Overall, both mineral wool waste types have homogenous chemical and physical properties as compared to many other mineral wastes which makes their utilization as a secondary raw material promising.
尽管矿棉废料在建筑和拆除废物 (CDW) 总量中仅占很小的一部分,但由于其低堆积密度,需要大量的运输和填埋能力,其利用率与其他 CDW 类型相比仍然较低。为了利用这种废物,了解其物理和化学性质至关重要,例如将其用作复合材料中的纤维增强材料或作为辅助胶凝材料。在这里,我们对从欧洲各地不同地点收集的 15 个玻璃棉和 12 个岩棉样本进行了化学和物理特性分析。此外,还介绍了从文献中获得的 61 个玻璃和岩棉样本的化学成分。玻璃棉样本的化学成分变化不大,类似于典型的钠钙硅酸盐玻璃的组成。岩棉的组成类似于玄武岩玻璃,但在钙、镁和铁含量方面存在样品间的差异。矿棉中存在潜在的有毒元素,如 Cr、Ba 和 Ni,但浓度较低(<0.2%)。这两种类型的羊毛都含有有机树脂,在加热或与碱性溶液接触时可能会分解成更小的分子碎片和氨。尽管矿棉的年龄和类型不同,但矿棉废料的长度和宽度分布相对相似。总体而言,与许多其他矿物废料相比,这两种矿棉废料类型具有相似的化学和物理性质,这使得它们作为二次原料的利用具有很大的前景。