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MPS/C（M = Ni和Sn）杂化材料的简便合成及其在锂离子电池中的应用

Facile Synthesis of MPS/C (M = Ni and Sn) Hybrid Materials and Their Application in Lithium-Ion Batteries.

作者信息

Liu Xianyu, Najam Tayyaba, Yasin Ghulam, Kumar Mohan, Wang Miao

机构信息

School of Chemistry and Chemical Engineering, Lanzhou City University, Lanzhou 730070, China.

Institute for Advanced Study, Shenzhen University, Shenzhen 518060, China.

出版信息

ACS Omega. 2021 Jun 29;6(27):17247-17254. doi: 10.1021/acsomega.1c01042. eCollection 2021 Jul 13.

DOI:10.1021/acsomega.1c01042
PMID:34278111
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8280674/
Abstract

Herein, we successfully synthesized two novel metal thiophosphites (MTPs) hybridized with carbon, that is, NiPS/C and SnPS/C composites, via an environment-friendly and cost-effective approach without harsh reaction conditions. Subsequently, the electrochemical performances of NiPS/C and SnPS/C composites have been investigated in coin-cells, and it is revealed that MTPs/C have a significantly higher Li-storage capacity and better stability compared to the MTPs without carbon. Moreover, the SnPS/C electrode shows a lower internal resistance and a better rate performance compared to NiPS/C. We employed extensive ex situ experiments to characterize the materials and interpreted the remarkably improved performance of MTPs/C.

摘要

在此，我们通过一种环境友好且经济高效的方法，在无苛刻反应条件下成功合成了两种与碳杂化的新型金属硫代亚磷酸盐（MTPs），即NiPS/C和SnPS/C复合材料。随后，在硬币电池中研究了NiPS/C和SnPS/C复合材料的电化学性能，结果表明，与不含碳的MTPs相比，MTPs/C具有显著更高的锂存储容量和更好的稳定性。此外，与NiPS/C相比，SnPS/C电极显示出更低的内阻和更好的倍率性能。我们采用了广泛的非原位实验来表征材料，并解释了MTPs/C性能显著提高的原因。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/fbdc9e8ecd6a/ao1c01042_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/78eb7ea2c620/ao1c01042_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/e6e7c6cdd690/ao1c01042_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/8ac119aef799/ao1c01042_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/ddc66e202cd9/ao1c01042_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/bee66500fa58/ao1c01042_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/fbdc9e8ecd6a/ao1c01042_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/78eb7ea2c620/ao1c01042_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/e6e7c6cdd690/ao1c01042_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/8ac119aef799/ao1c01042_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/ddc66e202cd9/ao1c01042_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/bee66500fa58/ao1c01042_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ffa/8280674/fbdc9e8ecd6a/ao1c01042_0006.jpg

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Few-layer NiPS nanosheets as bifunctional materials for Li-ion storage and oxygen evolution reaction.
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