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具有滑动环交联的聚合物网络的柔软性、弹性和韧性

Softness, Elasticity, and Toughness of Polymer Networks with Slide-Ring Cross-Links.

作者信息

Mayumi Koichi, Liu Chang, Yasuda Yusuke, Ito Kohzo

机构信息

The Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581, Japan.

Material Innovation Research Center (MIRC), Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan.

出版信息

Gels. 2021 Jul 13;7(3):91. doi: 10.3390/gels7030091.

Abstract

Slide-ring (SR) gels cross-linked by ring molecules are characterized by softness (low Young's modulus), elasticity (low hysteresis loss), and toughness (large fracture energy). In this article, the mechanical and fracture properties of SR gels are reviewed to clarify the physical understanding of the relationship between the molecular-level sliding dynamics of the slide-ring cross-links and macroscopic properties of SR gels. The low Young's modulus and large fracture energy of SR gels are expressed by simple equations as a function of the degree of sliding movement. The dynamic fracture behaviors of SR gels gives us the time scale of the sliding dynamics of the cross-links, which is at the micro-sec scale. The fast sliding motion of the cross-links leads to the elasticity of the SR gels. The SR concept can be applied to solvent-free elastomers and composite materials.

摘要

由环状分子交联而成的滑环(SR)凝胶具有柔软性(低杨氏模量)、弹性(低滞后损耗)和韧性(大断裂能)的特点。在本文中,对SR凝胶的力学和断裂性能进行了综述,以阐明对滑环交联的分子级滑动动力学与SR凝胶宏观性能之间关系的物理理解。SR凝胶的低杨氏模量和大断裂能通过简单方程表示为滑动运动程度的函数。SR凝胶的动态断裂行为为我们提供了交联的滑动动力学的时间尺度,其处于微秒尺度。交联的快速滑动运动导致了SR凝胶的弹性。SR概念可应用于无溶剂弹性体和复合材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1838/8293080/4de4e12dd268/gels-07-00091-g001.jpg

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本文引用的文献

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ACS Macro Lett. 2017 Dec 19;6(12):1409-1413. doi: 10.1021/acsmacrolett.7b00729. Epub 2017 Dec 4.
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