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评估基于低成本传感器的甲烷监测系统在连续多通道采样中的适用性。

Assessment of the applicability of a low-cost sensor-based methane monitoring system for continuous multi-channel sampling.

机构信息

Department of Plant Physiology, Umeå University, 901 87, Umeå, Sweden.

Graduate School of Science and Engineering, Saitama University, 255 Shimo-Okubo, Sakura-ku, Saitama, 338-8570, Japan.

出版信息

Environ Monit Assess. 2021 Jul 23;193(8):509. doi: 10.1007/s10661-021-09290-w.

Abstract

Systems that are made of several low-cost gas sensors with automatic gas sampling may have the potential to serve as reliable fast methane analyzers. However, there is a lack of reports about such types of systems evaluated under field conditions. Here, we developed a continuous methane monitoring system with automated gas sampling unit using low-cost gas sensors, TGS 2611 and MQ-4, that use a simple cloud-based data acquisition platform. We verified the consistency, repeatability, and reproducibility of the data obtained by TGS 2611 and MQ-4 low-cost gas sensors by measuring high- and low-concentration methane samples. The normalized root-mean-square errors (NRMSEs) of the samples with high methane concentrations, [CH] of 3, 4, 6, and 7%, were 0.0788, 0.0696, 0.1198, and 0.0719 for the TGS 2611 sensor, respectively, and were confirmed using a gas chromatograph as a reference analyzer. The NRMSEs of the samples with low [CH] of 0.096, 0.145, 0.193, and 0.241% measured by the TGS 2611 sensor were 0.0641, 0.1749, 0.0157, and 0.1613, whereas those NRMSEs of the same concentrations measured by the MQ-4 sensor were 0.3143, 0.5766, 0.6301, and 0.6859, respectively. Laboratory-scale anaerobic digesters were tested using the developed system. The anaerobic digesters were continuously operated for 2 months, demonstrating the potential use of sensors for detecting and monitoring methane in the field level application. This study utilized a unique way to combine the advantages of low-cost sensors and develop a reliable monitoring system by minimizing drawbacks of low-cost sensors.

摘要

由多个低成本气体传感器组成并具有自动气体采样功能的系统,可能具有成为可靠的快速甲烷分析仪的潜力。然而,在现场条件下评估此类系统的报告很少。在这里,我们使用低成本气体传感器 TGS 2611 和 MQ-4 开发了一种带有自动气体采样单元的连续甲烷监测系统,该系统使用简单的基于云的数据采集平台。我们通过测量高浓度和低浓度甲烷样品来验证 TGS 2611 和 MQ-4 低成本气体传感器获得的数据的一致性、重复性和再现性。TGS 2611 传感器对高甲烷浓度([CH]为 3、4、6 和 7%)的样品的归一化均方根误差(NRMSE)分别为 0.0788、0.0696、0.1198 和 0.0719,并用气相色谱仪作为参考分析仪进行了验证。TGS 2611 传感器测量的低 [CH](0.096、0.145、0.193 和 0.241%)样品的 NRMSE 分别为 0.0641、0.1749、0.0157 和 0.1613,而 MQ-4 传感器测量的相同浓度的 NRMSE 分别为 0.3143、0.5766、0.6301 和 0.6859。使用开发的系统对实验室规模的厌氧消化器进行了测试。连续运行 2 个月的厌氧消化器证明了传感器在现场水平应用中检测和监测甲烷的潜力。本研究利用一种独特的方法,结合低成本传感器的优势,并通过最小化低成本传感器的缺点来开发可靠的监测系统。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b7da/8302541/43202824a6c0/10661_2021_9290_Fig1_HTML.jpg

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