Influence of Phase Transitions on Electrostrictive and Piezoelectric Characteristics in PMN-30PT Single Crystals.

The ultrahigh electrostrain and piezoelectric constant () in relaxor piezoelectric PMN-30PT single crystals are closely related to the coexistence and transition of multiple phases at the morphotropic phase boundary (MPB). However, the key mechanisms underlying the stability of the phases and their transitions are yet to be fully understood. In this work, we undertake a systematic study of the influences of phase transitions on the electrostrictive and piezoelectric behaviors in ⟨001⟩-, ⟨011⟩-, and ⟨111⟩-oriented PMN-30PT single crystals. We first classify the various phase transitions within the quasi-MPB in electric field-temperature phase diagrams as either dominated by the electric field or by temperature. We find that the electrostrain reaches a maximum at each phase transition, especially in the electric-field-dominated transitions, whereas only peaks at specific phase transitions. In particular, the electrostrain in the ⟨001⟩ crystal reaches a maximum of = 0.52% at 55 °C under an external electric field with = 15 kV/cm, primarily due to a joint contribution of the electric field-dominated rhombohedral-monoclinic and monoclinic-tetragonal phase transitions at the quasi-MPB. An ultrahigh (∼2460 pC/N) only occurs at the rhombohedral-monoclinic phase transition in the ⟨001⟩ crystal and at the rhombohedral-orthorhombic transition in the ⟨011⟩ crystal ( ∼ 1500 pC/N) due to the lower energy barriers. The temperature-dominated phase transitions also contribute toward minor peaks in electrostrain and/or . This work provides a deeper and quantitative understanding of the microscopic mechanisms underlying electrostrictive and piezoelectric behaviors relevant for the design of high-performance materials.