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制备一维CoFe/C@MoS复合材料作为高效电磁波吸收材料。

Fabrication of one-dimensional CoFe/C@MoS composites as efficient electromagnetic wave absorption materials.

作者信息

Liao Zijian, Ma Mingliang, Tong Zhouyu, Bi Yuxin, Chung Kwok L, Qiao Mingtao, Ma Yong, Ma Aijie, Wu Guanglei, Zhong Xiang, Sun Ranran

机构信息

School of Civil Engineering, Qingdao University of Technology, Qingdao 266033, People's Republic of China.

出版信息

Dalton Trans. 2021 Sep 7;50(33):11640-11649. doi: 10.1039/d1dt01915e. Epub 2021 Aug 6.

Abstract

New types of electromagnetic (EM) wave absorption materials with a light weight, strong absorption ability and wide absorption frequency have been widely explored. Nevertheless, it is still an intractable challenge to design the structure of the materials and rationalize multiple components. In this work, one-dimensional (1D) CoFe/C@MoS composites were prepared via electrospinning technology, high-temperature carbonization and hydrothermal method. SEM and TEM images reveal that the as-prepared CoFe/C fibers with a 1D structure are well coated with MoS. The excellent absorption performance of the composites is mainly attributed to the 1D structure and the ideal impedance matching. CoFe/C@MoS composites show strong absorption ability with an optimal reflection loss (RL) of -66.8 dB (13.28 GHz) at a matching thickness of 2.12 mm. Meanwhile, the composite possesses an effective absorption frequency range between 10.70 and 16.02 GHz with a bandwidth of 5.32 GHz. These results indicate that CoFe/C@MoS composites will become promising lightweight and highly efficient MA materials.

摘要

新型轻质、强吸收能力且吸收频率宽的电磁波吸收材料已得到广泛研究。然而,设计材料结构并合理配置多种成分仍是一个棘手的挑战。在这项工作中,通过静电纺丝技术、高温碳化和水热法制备了一维(1D)CoFe/C@MoS复合材料。扫描电子显微镜(SEM)和透射电子显微镜(TEM)图像显示,所制备的具有一维结构的CoFe/C纤维被MoS很好地包覆。复合材料优异的吸收性能主要归因于一维结构和理想的阻抗匹配。CoFe/C@MoS复合材料表现出很强的吸收能力,在匹配厚度为2.12 mm时,最佳反射损耗(RL)为-66.8 dB(13.28 GHz)。同时,该复合材料的有效吸收频率范围在10.70至16.02 GHz之间,带宽为5.32 GHz。这些结果表明,CoFe/C@MoS复合材料将成为有前景的轻质高效吸波材料。

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