Wang Yutong, Lu Lichang, Hao Yu, Wu Yujie, Li Yuanzhe
College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China.
School of Advanced Materials Science and Engineering, Loughborough University, Loughborough LE11 3TT, United Kingdom.
ACS Omega. 2021 Jul 20;6(30):19705-19716. doi: 10.1021/acsomega.1c02354. eCollection 2021 Aug 3.
With the people's awareness of the "3Rs" in recent years, using recycled high-density polyethylene (HDPE) and random copolymer polypropylene (PPR) as the base materials for piping fabrication has become a mainstream in scholastic path and industrial engineering. In this study, the modified maleic anhydride-grafted polyethylene (POE--MAH) compatibilizer was fabricated to increase the interfacial adhesion and dispersion. With the surface modification of calcium carbonate, a POE--MAH/CaCO/HDPE polymer composite has been prepared. Such modified polymer composites can further reinforce the processing performance and mechanical properties of recycled HDPE and PPR materials. The results indicated that with the introduction of the polymer composite, significant enhancement of the recycled materials in the aspects of processability, tensile strength, flexural performance, and impact force could be obtained, and the POE--MAH/CaCO/HDPE polymer composite would contribute to the impressive balance between high rigidity and toughness. In addition, the feasibility and mechanical properties of the recycled HDPE-PPR-POE--MAH/CaCO/HDPE blended system were also studied: with the help of a composite microcapsule, the gap of mechanical capacity between recycled and non-recycled materials was further reduced, and such a blended system was capable of being commercialized in the piping industry.
近年来,随着人们对“3R”理念的认识,使用回收的高密度聚乙烯(HDPE)和无规共聚聚丙烯(PPR)作为管道制造的基础材料已成为学术研究和工业工程中的主流。在本研究中,制备了改性马来酸酐接枝聚乙烯(POE-MAH)增容剂以提高界面附着力和分散性。通过对碳酸钙进行表面改性,制备了POE-MAH/CaCO/HDPE聚合物复合材料。这种改性聚合物复合材料可以进一步增强回收HDPE和PPR材料的加工性能和机械性能。结果表明,引入聚合物复合材料后,回收材料在加工性能、拉伸强度、弯曲性能和冲击力方面有显著提高,且POE-MAH/CaCO/HDPE聚合物复合材料有助于在高刚性和韧性之间取得令人满意的平衡。此外,还研究了回收HDPE-PPR-POE-MAH/CaCO/HDPE共混体系的可行性和机械性能:借助复合微胶囊,回收材料与未回收材料之间的机械性能差距进一步缩小,且这种共混体系能够在管道行业实现商业化。