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暴露于游泳池老化环境中的聚合物材料的性能:关注确保舒适性和耐用性的特性。

Behavior of Polymer Materials Exposed to Aging in the Swimming Pool: Focus on Properties That Assure Comfort and Durability.

作者信息

Salopek Čubrić Ivana, Čubrić Goran, Potočić Matković Vesna Marija

机构信息

Faculty of Textile Technology, University of Zagreb, 10000 Zagreb, Croatia.

出版信息

Polymers (Basel). 2021 Jul 22;13(15):2414. doi: 10.3390/polym13152414.

Abstract

The degradation of polyamide (PA) and polyester (PES) polymers is under intense study due to growing concerns about the accumulation of plastics in soils and oceans. Previous studies confirm that ageing degrades PA and PES at the molecular level. However, researchers have not addressed the development of protocols for aging textile materials in swimming pools, and few data are available on the effects of aging on comfort and durability. This research addresses the development of the aging protocol for PA and PES swimwear materials, its implementation, and the evaluation of properties that assure comfort and durability after specific periods of exposure. The tests include microscopic analysis, tensile tests, determination of fluid transport phases and drying period. The results revealed changes in the surface of the material in terms of fibrillation (more pronounced after outdoor aging). There is a positive correlation between the exposure duration and the breaking force (R ranges from 0.85 to 0.98), with a stronger correlation for the PA materials. The decrease in breaking force due to aging is up to 40%, indicating significantly reduced durability. The change in breaking force follows the changes in mass (R = 0.867). In terms of comfort assurance, outdoor aging of materials should have a greater negative impact than indoor ageing.

摘要

由于人们对土壤和海洋中塑料积累的担忧日益增加,聚酰胺(PA)和聚酯(PES)聚合物的降解受到了广泛研究。先前的研究证实,老化会在分子水平上降解PA和PES。然而,研究人员尚未探讨在游泳池中对纺织材料进行老化处理的方案,关于老化对舒适性和耐用性影响的数据也很少。本研究旨在开发PA和PES泳衣材料的老化方案,实施该方案,并评估在特定暴露时间后确保舒适性和耐用性的性能。测试包括微观分析、拉伸试验、流体传输阶段测定和干燥时间测定。结果显示,材料表面在原纤化方面发生了变化(户外老化后更为明显)。暴露持续时间与断裂力之间存在正相关(R值在0.85至0.98之间),PA材料的相关性更强。老化导致的断裂力下降高达40%,表明耐用性显著降低。断裂力的变化与质量变化一致(R = 0.867)。在舒适性保证方面,材料的户外老化比室内老化产生的负面影响更大。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8cea/8347283/49bab69a5dac/polymers-13-02414-g001.jpg

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