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评估不同环境下老化导致的聚合物材料性能变化。

Evaluation of Changes in Polymer Material Properties Due to Aging in Different Environments.

作者信息

Čubrić Ivana Salopek, Čubrić Goran, Katić Križmančić Ines, Kovačević Monika

机构信息

Department of Textile Design and Management, Faculty of Textile Technology, University of Zagreb, 10000 Zagreb, Croatia.

Department of Clothing Technology, Faculty of Textile Technology, University of Zagreb, 10000 Zagreb, Croatia.

出版信息

Polymers (Basel). 2022 Apr 21;14(9):1682. doi: 10.3390/polym14091682.

Abstract

With the increase in awareness of the importance of engagement in physical activities, high requirements have been placed on polymers intended for use in sports. A number of authors investigated the influence of aging factors on the performance of the polymer. Still, there is a lack of aging protocols that would be product-centered, especially when high performance is imperative. This paper presents a new approach to polymer aging and examines the change of the identified set of properties due to aging under different conditions, and the duration of each (topography, thickness, moisture management, elongation, and bursting force). The results of the testing revealed the increase in thickness due to exposure, especially to the sun-exposed materials. The ability of materials to elongate until the moment of rupture decreases due to exposure to the sun (strong relationship to the time of exposure; R reaches 0.99) and the bursting force (up to 6.8%). Furthermore, results indicate the significantly impaired capacity of the polymer material to absorb moisture. The results of measurements indicated (derived) by spectroscopic studies, based on the ATR-FTIR (attenuated total reflectance) method, showed that there was no detectable influence of aging in the sun or shade on the chemical structure of polyester samples.

摘要

随着人们对参与体育活动重要性的认识不断提高,对用于体育的聚合物提出了很高的要求。许多作者研究了老化因素对聚合物性能的影响。然而,仍然缺乏以产品为中心的老化方案,尤其是在高性能至关重要的情况下。本文提出了一种聚合物老化的新方法,并研究了在不同条件下老化以及每种条件(形貌、厚度、水分管理、伸长率和爆破力)持续时间导致的一组已确定性能的变化。测试结果表明,暴露会导致厚度增加,尤其是暴露在阳光下的材料。材料在断裂前的伸长能力因暴露在阳光下而降低(与暴露时间有很强的关系;R达到0.99),爆破力也降低(高达6.8%)。此外,结果表明聚合物材料吸收水分的能力明显受损。基于衰减全反射傅里叶变换红外光谱(ATR-FTIR)方法的光谱研究得出的测量结果表明,在阳光下或阴凉处老化对聚酯样品的化学结构没有可检测到的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13d3/9102830/7220c3aecf31/polymers-14-01682-g001.jpg

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