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基于氧化锌纳米线/聚二甲基硅氧烷混合介电复合材料及固定化碳纳米管随机网络柔性电极的可穿戴压力/触摸传感器

Wearable Pressure/Touch Sensors Based on Hybrid Dielectric Composites of Zinc Oxide Nanowires/Poly(dimethylsiloxane) and Flexible Electrodes of Immobilized Carbon Nanotube Random Networks.

作者信息

Kang Byeong-Cheol, Park Sang-Joon, Ha Tae-Jun

机构信息

Department of Electronic Materials Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.

出版信息

ACS Appl Mater Interfaces. 2021 Sep 8;13(35):42014-42023. doi: 10.1021/acsami.1c10961. Epub 2021 Aug 27.

DOI:10.1021/acsami.1c10961
PMID:34450010
Abstract

Capacitive-type physical sensors based on hybrid dielectric composites of zinc oxide nanowires/poly(dimethylsiloxane) (ZnO NWs@PDMS) and flexible electrodes of immobilized carbon nanotube (CNT) random networks, which are highly sensitive to pressure and touch stimuli, are demonstrated. Immobilized CNT random networks densely entangled in a Nafion matrix improve the electrical stability of wearable pressure sensors against mechanical stress with a bending radius of 5 mm. The effect of ZnO NW incorporation into PDMS on the sensing performance of pressure sensors is investigated, which results in a significantly enhanced sensitivity of 8.77 × 10 Pa in low-pressure regions, compared to pristine PDMS (1.32 × 10 Pa). This improvement is attributed to the increase in the effective dielectric constant (ε) of the hybrid dielectric composites with their piezoelectric properties. In addition, wearable pressure/touch sensor arrays capable of detecting ultralow pressures (down to 20 Pa) and the real-time identification of touch and pressure stimuli via different sensing mechanisms are demonstrated. We believe that the multifunctionality introduced by the proposed sensors can extend the potential of physical sensor applications, while they are suitable for integration with wearable electronics based on hybrid nanocomposites and interfaces.

摘要

展示了基于氧化锌纳米线/聚二甲基硅氧烷(ZnO NWs@PDMS)混合介电复合材料和固定化碳纳米管(CNT)随机网络柔性电极的电容式物理传感器,该传感器对压力和触摸刺激高度敏感。密集缠结在Nafion基质中的固定化CNT随机网络提高了可穿戴压力传感器在弯曲半径为5 mm的机械应力下的电气稳定性。研究了将ZnO NW掺入PDMS对压力传感器传感性能的影响,与原始PDMS(1.32×10 Pa)相比,在低压区域其灵敏度显著提高至8.77×10 Pa。这种改进归因于具有压电特性的混合介电复合材料的有效介电常数(ε)增加。此外,还展示了能够检测超低压力(低至20 Pa)以及通过不同传感机制实时识别触摸和压力刺激的可穿戴压力/触摸传感器阵列。我们相信,所提出的传感器所引入的多功能性可以扩展物理传感器应用的潜力,同时它们适用于与基于混合纳米复合材料和界面的可穿戴电子产品集成。

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