Institute of Physical Chemistry "Ilie Murgulescu", Romanian Academy, 202 Splaiul Independentei, 060021 Bucharest, Romania.
Molecules. 2023 Jun 9;28(12):4674. doi: 10.3390/molecules28124674.
This review addresses the importance of Zn for obtaining multifunctional materials with interesting properties by following certain preparation strategies: choosing the appropriate synthesis route, doping and co-doping of ZnO films to achieve conductive oxide materials with p- or n-type conductivity, and finally adding polymers in the oxide systems for piezoelectricity enhancement. We mainly followed the results of studies of the last ten years through chemical routes, especially by sol-gel and hydrothermal synthesis. Zinc is an essential element that has a special importance for developing multifunctional materials with various applications. ZnO can be used for the deposition of thin films or for obtaining mixed layers by combining ZnO with other oxides (ZnO-SnO, ZnO-CuO). Also, composite films can be achieved by mixing ZnO with polymers. It can be doped with metals (Li, Na, Mg, Al) or non-metals (B, N, P). Zn is easily incorporated in a matrix and therefore it can be used as a dopant for other oxidic materials, such as: ITO, CuO, BiFeO and NiO. ZnO can be very useful as a seed layer, for good adherence of the main layer to the substrate, generating nucleation sites for nanowires growth. Thanks to its interesting properties, ZnO is a material with multiple applications in various fields: sensing technology, piezoelectric devices, transparent conductive oxides, solar cells, and photoluminescence applications. Its versatility is the main message of this review.
这篇综述探讨了 Zn 通过以下特定制备策略获得多功能材料的重要性:选择适当的合成路线、掺杂和共掺杂 ZnO 薄膜以获得具有 p 型或 n 型导电性的导电氧化物材料,最后在氧化物体系中添加聚合物以提高压电性能。我们主要通过化学途径,特别是溶胶-凝胶和水热合成,遵循了过去十年的研究结果。锌是一种必需元素,对于开发具有各种应用的多功能材料具有特殊的重要性。ZnO 可用于沉积薄膜,或通过将 ZnO 与其他氧化物(ZnO-SnO、ZnO-CuO)结合来获得混合层。此外,还可以通过混合 ZnO 与聚合物来获得复合膜。它可以掺杂金属(Li、Na、Mg、Al)或非金属(B、N、P)。Zn 很容易掺入基质中,因此它可用作其他氧化材料(如 ITO、CuO、BiFeO 和 NiO)的掺杂剂。ZnO 可用作种子层,以提高主层与衬底的附着力,为纳米线生长生成成核点。由于其有趣的特性,ZnO 是一种在各个领域具有多种应用的材料:感测技术、压电器件、透明导电氧化物、太阳能电池和光致发光应用。其多功能性是这篇综述的主要信息。