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制备并表征了添加 TiO 纳米粒子和蕹菜多糖的绿豆淀粉膜。

Preparation and characterization of hyacinth bean starch film incorporated with TiO nanoparticles and Mesona chinensis Benth polysaccharide.

机构信息

State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, China.

State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, China.

出版信息

Int J Biol Macromol. 2021 Nov 1;190:151-158. doi: 10.1016/j.ijbiomac.2021.08.180. Epub 2021 Sep 2.

Abstract

Hyacinth bean starch (HBS) was used to prepare nanocomposite films with the reinforcement agent of nanotitanium oxide (TiO-N) and Mesona chinensis Benth polysaccharide (MCP). The effects of TiO-N and MCP on the moisture combination, rheological properties of film-forming solutions (FFS) and physiochemical properties of films were investigated. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) revealed that HBS, TiO-N and MCP had good compatibility, while no novel absorption peak in FTIR spectra, and characteristic peaks of TiO-N were found in XRD patterns of composite films. Contact angle of HBS/TiO-N/M3 film increased from 65.6° to 90.9°, which illustrated that TiO-N and MCP effectively enhanced hydrophobicity of films. TiO-N and MCP positively affected anti-UV light ability of HBS films by resisting most of invisible light. Furthermore, stable and compact network structures were formed by the synergistic effect of TiO-N and MCP, thereby elongation to break was increased from 17.123% to 28.603% significantly, and heat resistance was enhanced clearly. This study prepared a nanocomposite HBS-based films based TiO-N and MCP, which had guiding significance for development of functional films and combination of polysaccharides and metallic oxide.

摘要

木豆淀粉(HBS)被用于制备纳米复合材料薄膜,增强剂为纳米氧化钛(TiO-N)和蕹菜多糖(MCP)。研究了 TiO-N 和 MCP 对成膜溶液(FFS)的水分结合、流变性能以及薄膜的物理化学性能的影响。傅里叶变换红外光谱(FTIR)、X 射线衍射(XRD)表明 HBS、TiO-N 和 MCP 具有良好的相容性,而在 FTIR 光谱中没有新的吸收峰,在复合薄膜的 XRD 图谱中发现了 TiO-N 的特征峰。HBS/TiO-N/M3 薄膜的接触角从 65.6°增加到 90.9°,表明 TiO-N 和 MCP 有效地提高了薄膜的疏水性。TiO-N 和 MCP 通过抵抗大部分可见光,对 HBS 薄膜的抗紫外线能力有积极影响。此外,TiO-N 和 MCP 的协同作用形成了稳定而致密的网络结构,从而使断裂伸长率从 17.123%显著增加到 28.603%,耐热性明显提高。本研究基于 TiO-N 和 MCP 制备了纳米复合 HBS 基薄膜,这对功能性薄膜的开发以及多糖和金属氧化物的结合具有指导意义。

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