State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, China.
State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, China.
Int J Biol Macromol. 2021 Nov 1;190:151-158. doi: 10.1016/j.ijbiomac.2021.08.180. Epub 2021 Sep 2.
Hyacinth bean starch (HBS) was used to prepare nanocomposite films with the reinforcement agent of nanotitanium oxide (TiO-N) and Mesona chinensis Benth polysaccharide (MCP). The effects of TiO-N and MCP on the moisture combination, rheological properties of film-forming solutions (FFS) and physiochemical properties of films were investigated. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) revealed that HBS, TiO-N and MCP had good compatibility, while no novel absorption peak in FTIR spectra, and characteristic peaks of TiO-N were found in XRD patterns of composite films. Contact angle of HBS/TiO-N/M3 film increased from 65.6° to 90.9°, which illustrated that TiO-N and MCP effectively enhanced hydrophobicity of films. TiO-N and MCP positively affected anti-UV light ability of HBS films by resisting most of invisible light. Furthermore, stable and compact network structures were formed by the synergistic effect of TiO-N and MCP, thereby elongation to break was increased from 17.123% to 28.603% significantly, and heat resistance was enhanced clearly. This study prepared a nanocomposite HBS-based films based TiO-N and MCP, which had guiding significance for development of functional films and combination of polysaccharides and metallic oxide.
木豆淀粉(HBS)被用于制备纳米复合材料薄膜,增强剂为纳米氧化钛(TiO-N)和蕹菜多糖(MCP)。研究了 TiO-N 和 MCP 对成膜溶液(FFS)的水分结合、流变性能以及薄膜的物理化学性能的影响。傅里叶变换红外光谱(FTIR)、X 射线衍射(XRD)表明 HBS、TiO-N 和 MCP 具有良好的相容性,而在 FTIR 光谱中没有新的吸收峰,在复合薄膜的 XRD 图谱中发现了 TiO-N 的特征峰。HBS/TiO-N/M3 薄膜的接触角从 65.6°增加到 90.9°,表明 TiO-N 和 MCP 有效地提高了薄膜的疏水性。TiO-N 和 MCP 通过抵抗大部分可见光,对 HBS 薄膜的抗紫外线能力有积极影响。此外,TiO-N 和 MCP 的协同作用形成了稳定而致密的网络结构,从而使断裂伸长率从 17.123%显著增加到 28.603%,耐热性明显提高。本研究基于 TiO-N 和 MCP 制备了纳米复合 HBS 基薄膜,这对功能性薄膜的开发以及多糖和金属氧化物的结合具有指导意义。