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用于降解四环素抗生素的异质结光催化剂：综述

Heterojunction photocatalysts for degradation of the tetracycline antibiotic: a review.

作者信息

He Xinghou, Kai Tianhan, Ding Ping

机构信息

Central South University Xiangya School of Public Health, Changsha, 410078 Hunan China.

Hunan Provincial Key Laboratory of Clinical Epidemiology, Changsha, 410078 Hunan China.

出版信息

Environ Chem Lett. 2021;19(6):4563-4601. doi: 10.1007/s10311-021-01295-8. Epub 2021 Aug 30.

DOI:10.1007/s10311-021-01295-8
PMID:34483792
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8403697/
Abstract

Antibiotic pollution is a major health issue inducing antibiotic resistance and the inefficiency of actual drugs, thus calling for improved methods to clean water and wastewater. Here we review the recent development of heterojunction photocatalysis and application in degrading tetracycline. We discuss mechanisms for separating photogenerated electron-hole pairs in different heterojunction systems such as traditional, p-n, direct Z-scheme, step-scheme, Schottky, and surface heterojunction. Degradation pathways of tetracycline during photocatalysis are presented. We compare the efficiency of tetracycline removal by various heterojunctions using quantum efficiency, space time yield, and figures of merit. Implications for the treatment of antibiotic-contaminated wastewater are discussed.

摘要

抗生素污染是一个重大的健康问题，它会导致抗生素耐药性以及现有药物失效，因此需要改进清洁水和废水的方法。在此，我们综述了异质结光催化的最新进展及其在降解四环素方面的应用。我们讨论了不同异质结体系（如传统异质结、p-n异质结、直接Z型异质结、阶梯型异质结、肖特基异质结和表面异质结）中光生电子-空穴对的分离机制。介绍了光催化过程中四环素的降解途径。我们使用量子效率、时空产率和品质因数比较了各种异质结对四环素的去除效率。还讨论了其对处理抗生素污染废水的意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/3d27ffcecd30/10311_2021_1295_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/f60dd0c9cdd0/10311_2021_1295_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/b858a8315655/10311_2021_1295_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/dfc8250dbec8/10311_2021_1295_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/b8d5580a31dc/10311_2021_1295_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/4b0852961c6d/10311_2021_1295_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/3d27ffcecd30/10311_2021_1295_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/f60dd0c9cdd0/10311_2021_1295_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/b858a8315655/10311_2021_1295_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/dfc8250dbec8/10311_2021_1295_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/b8d5580a31dc/10311_2021_1295_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/4b0852961c6d/10311_2021_1295_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a0/8403697/3d27ffcecd30/10311_2021_1295_Fig7_HTML.jpg

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