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碳纳米管辅助多环芳烃电氧化介导生物电化学的研究进展。

Insights into carbon nanotube-assisted electro-oxidation of polycyclic aromatic hydrocarbons for mediated bioelectrocatalysis.

机构信息

Département de Chimie Moléculaire (DCM), Univ. Grenoble Alpes-CNRS, 570 rue de la Chimie, Grenoble 38041, France. michael.holzinger@univ-grenoble-alpes.

Department of Chemistry (DQI), State University of Maringá, Colombo 5790, Maringá 87020-900, PR, Brazil.

出版信息

Chem Commun (Camb). 2021 Sep 6;57(71):8957-8960. doi: 10.1039/d1cc02958d.

DOI:10.1039/d1cc02958d
PMID:34486593
Abstract

A series of polycyclic aromatics, naphthalene, phenanthrene, perylene, pyrene, 1-pyrenebutyric acid -hydroxysuccinimide ester (pyrene NHS) and coronene, were immobilized π stacking on carbon nanotube (CNT) electrodes and electro-oxidized in aqueous solutions. The obtained quinones were characterized and evaluated for the mediated electron transfer with FAD dependent glucose dehydrogenase during catalytic glucose oxidation.

摘要

一系列多环芳烃,萘、菲、苝、芘、1-芘丁酸-琥珀酰亚胺酯(芘 NHS)和并四苯,被固定在碳纳米管(CNT)电极上,并在水溶液中进行电氧化。所得醌被表征,并在催化葡萄糖氧化过程中与 FAD 依赖性葡萄糖脱氢酶进行介导电子转移进行了评估。

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