Jung Chunghwan, Kim Gyeongtae, Jeong Minsu, Jang Jaehyuck, Dong Zhaogang, Badloe Trevon, Yang Joel K W, Rho Junsuk
Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea.
Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea.
Chem Rev. 2021 Nov 10;121(21):13013-13050. doi: 10.1021/acs.chemrev.1c00294. Epub 2021 Sep 7.
Optically variable devices (OVDs) are in tremendous demand as optical indicators against the increasing threat of counterfeiting. Conventional OVDs are exposed to the danger of fraudulent replication with advances in printing technology and widespread copying methods of security features. Metasurfaces, two-dimensional arrays of subwavelength structures known as meta-atoms, have been nominated as a candidate for a new generation of OVDs as they exhibit exceptional behaviors that can provide a more robust solution for optical anti-counterfeiting. Unlike conventional OVDs, metasurface-driven OVDs (mOVDs) can contain multiple optical responses in a single device, making them difficult to reverse engineered. Well-known examples of mOVDs include ultrahigh-resolution structural color printing, various types of holography, and polarization encoding. In this review, we discuss the new generation of mOVDs. The fundamentals of plasmonic and dielectric metasurfaces are presented to explain how the optical responses of metasurfaces can be manipulated. Then, examples of monofunctional, tunable, and multifunctional mOVDs are discussed. We follow up with a discussion of the fabrication methods needed to realize these mOVDs, classified into prototyping and manufacturing techniques. Finally, we provide an outlook and classification of mOVDs with respect to their capacity and security level. We believe this newly proposed concept of OVDs may bring about a new era of optical anticounterfeit technology leveraging the novel concepts of nano-optics and nanotechnology.
随着防伪威胁的不断增加,光学可变装置(OVDs)作为光学指示器的需求巨大。随着印刷技术的进步和安全特征复制方法的广泛传播,传统的OVDs面临着被欺诈性复制的风险。超表面是由亚波长结构组成的二维阵列,被称为元原子,因其表现出的特殊行为可为光学防伪提供更强大的解决方案,已被提名为新一代OVDs的候选者。与传统的OVDs不同,基于超表面的OVDs(mOVDs)可以在单个装置中包含多种光学响应,这使得它们难以被逆向工程。mOVDs的著名例子包括超高分辨率结构彩色印刷、各种类型的全息术和偏振编码。在这篇综述中,我们讨论了新一代的mOVDs。介绍了等离子体和介电超表面的基本原理,以解释如何操纵超表面的光学响应。然后,讨论了单功能、可调谐和多功能mOVDs的例子。接着,我们讨论了实现这些mOVDs所需的制造方法,分为原型制作和制造技术。最后,我们根据mOVDs的容量和安全级别对其进行了展望和分类。我们相信,这种新提出的OVDs概念可能会利用纳米光学和纳米技术的新概念带来光学防伪技术的新时代。